π...π interaction assembled silver(I) complexes with the ligand 4′,5′-diaza-9′-(4,5-disubstituted-1,3-dithiol-2-ylidene)fluorene

被引：11
|
作者：
Zhu, QY
Dai, J [1 ]
Jia, DX
Cao, LH
Lin, HH
机构：
[1] Suzhou Univ, Dept Chem & Chem Engn, Suzhou 215006, Peoples R China
[2] Suzhou Univ, Key Lab Organ Synth Jiangsu Prov, Suzhou 215006, Peoples R China
来源：
POLYHEDRON | 2004年 / 23卷 / 14期
基金：
中国国家自然科学基金;
关键词：
diaza-fluorene; silver complexes; crystal structures; intermolecular interactions; electronic spectra;
D O I：
10.1016/j.poly.2004.07.007
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Six silver(I) complexes with a new type of ligand, 4',5'-diaza-9'-(4,5-disubstituted-1,3-dithiol-2-ylidene)fluorene (L-n, n = 1, Me; 2, Et; 3, Bu substituted) have been obtained. Two of the complexes [Ag(L-1)(2)]ClO4 (1) and [Ag(L-1)(2)]SO3CF3 (4) have been structurally characterized by single-crystal X-ray diffraction. All of the Ag(I) ions are coordinated linearly by two ligands and the cations take planar structures. These planes are further assembled into one dimensional columns by Ag-Ag weak bonds, pi-pi stacking and (AgN)-N-... interactions. The UV-Vis and fluorescence spectra of the complexes were studied and the ligand-centered energy levels are not changed dramatically when the complexes are formed. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码：2259 / 2264
页数：6
相关论文
共 50 条
  • [21] Synthesis, crystal structures, and characterization of 4,5-diaza-9-[4,5-bis(methylthio)-1,3-dithiol-2-ylidene]-fluorene (L) metal complexes [(TPyA)MII(L)](SbF6)2 (MII = Mn, Fe, Co; TPyA = tris(2-pyridylmethyl) amine)
    Culpitt, Tanner
    Guzei, Ilia A.
    Spencer, Lara C.
    Simonson, Andrew
    Miller, Joel S.
    Wimmer, Megan R.
    Nelson, Kendric J.
    INORGANICA CHIMICA ACTA, 2015, 427 : 162 - 167
  • [22] 2-[4,5-bis(n-pentylsulfanyl)-1,3-dithiol-2-ylidene]-1,3-dithiolo[4,5-c]pyrrole
    Nielsen, KA
    Bond, AD
    Jeppesen, JO
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : O1702 - O1703
  • [23] Synthesis of 4-(2-Hydroxy-5-methylphenyl)-1,3-Dithiol-2-ylidene Derivatives
    Lungu, Catalin Neculai
    Asaftei, Iuliean Vasile
    Sandu, Ion
    Chirita, Paul
    Bahrin, Lucian Gabriel
    REVISTA DE CHIMIE, 2019, 70 (05): : 1558 - 1560
  • [24] 5-(4,5-Ethylenedithio-1,3-dithiol-2-ylidene)-1,3,4,6-tetrathiapentalen-2-one (EDTO-TTP) and 5-[4,5-(ethene-1,2-diyldithio)-1,3-dithiol-2-ylidene]-1,3,4,6-tetrathiapentalen-2-one (VDTO-TTP)
    Chen, Hong-Feng
    Fang, Qi
    Yu, Wen-Tao
    Batsanov, Andrei S.
    Howard, Judith A. K.
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2009, 65 : O198 - O201
  • [25] Ethyl 2-[4,5-bis(butylsulfanyl)-1,3-dithiol-2-ylidene]-1,3-dithiolo[4,5-c]pyrrole-4-carboxylate
    Li, Dong-Feng
    Zhu, Xiao-Fei
    Guan, Shuang
    Hou, Rui-Bin
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O1400 - +
  • [26] Rhodium(I) and Silver(I) Complexes of 4,5-Dicyano-1,3-dimesityl- and 4,5-Dicyano-1,3-dineopentylimidazol-2-ylidene
    Baier, Heiko
    Kelling, Alexandra
    Jackstell, Ralf
    Holdt, Hans-Juergen
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2013, 639 (10): : 1731 - 1739
  • [27] Synthesis, Properties and Quantum Chemical Calculation of 3-(4,5-Dibenzyldithio-1,3-dithiol-2-ylidene)naphthopyranone
    Zhu, Yulan
    Xia, Ke
    Zhou, Xinxin
    Cao, Li
    Lu, Mingzhu
    Wang, Kun
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2012, 32 (04) : 714 - 718
  • [28] Synthesis and properties of novel crown ether-annelated 4′,5′-diaza-9′-(1,3-dithiole-2-ylidene)-fluorenes and their ruthenium(II) complexes
    Sako, Katsuya
    Kakehi, Toshiaki
    Nakano, Shota
    Oku, Hiroyuki
    Shen, Xu Feng
    Iwanaga, Tetsuo
    Yoshikawa, Manami
    Sugahara, Kouta
    Toyota, Shinji
    Takemura, Hiroyuki
    Shinmyozu, Teruo
    Shiotsuka, Michito
    Tatemitsu, Hitoshi
    TETRAHEDRON LETTERS, 2014, 55 (03) : 749 - 752
  • [29] Novel 4-(3-Bromo-2-hydroxy-5-methylphenyl)-1,3-Dithiol-2-ylidene Derivatives
    Gorodea, Ioana Aurelia
    Sandu, Ion
    Sarbu, Laura Gabriela
    REVISTA DE CHIMIE, 2017, 68 (09): : 1988 - 1991
  • [30] Optical study of two-dimensional organic metal (EO-TTP)2AsF6 (EO-TTP=2-(4,5-ethylenedioxy-1,3-dithiol-2-ylidene)-5-(1,3-dithiol-2-ylidene)-1,3,4,6-tetrathiapentalene)
    Drozdova, O
    Yakushi, K
    Misaki, Y
    Tanaka, K
    JOURNAL OF SOLID STATE CHEMISTRY, 2002, 168 (02) : 497 - 502
12345