Low-temperature Hydrogenation of Toluene by Electrolysis of Water with Hydrogen Permeable Palladium Membrane Electrode

被引：6

作者：

Sato, Takafumi ^{[1
]}

Takada, Ayaka ^{[1
]}

Itoh, Naotsugu ^{[1
]}

机构：

[1] Utsunomiya Univ, Dept Mat & Environm Chem, 7-1-2 Yoto, Utsunomiya, Tochigi 3218585, Japan

来源：

CHEMISTRY LETTERS | 2017年 / 46卷 / 04期

关键词：

Electrolysis of water; Hydrogenation of toluene; Palladium membrane electrode; SHEET ELECTRODE; PD SHEET; CATHODE; PERMEATION; REACTOR; STYRENE; ALLOY;

D O I：

10.1246/cl.161164

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hydrogenation of toluene proceeded with hydrogen derived from the electrolysis of water with an electrical cell that a hydrogen permeable palladium membrane was the cathode. The hydrogenation occurred with selectively permeated hydrogen through the membrane in a catalytic layer at more than 313K and the rate of hydrogenation increased with increasing temperature. This system was stable at least several hours and about a half of hydrogen produced by the electrolysis can be used for hydrogenation.

引用

页码：477 / 480

页数：4

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