Efficient synthesis of propargylamines from terminal alkynes, dichloromethane and tertiary amines over silver catalysts

被引:44
|
作者
Chen, Xiuling [1 ]
Chen, Tieqiao [1 ]
Zhou, Yongbo [1 ]
Au, Chak-Tong [1 ,2 ]
Han, Li-Biao [1 ]
Yin, Shuang-Feng [1 ]
机构
[1] Hunan Univ, Coll Chem & Chem Engn, State Key Lab Chemo Biosensing & Chemometr, Changsha 410082, Hunan, Peoples R China
[2] Hong Kong Baptist Univ, Dept Chem, Kowloon Tong, Hong Kong, Peoples R China
关键词
3-COMPONENT COUPLING REACTION; H BONDS ADJACENT; C-H; DIRECT-ADDITION; ENANTIOSELECTIVE SYNTHESIS; MILD CONDITIONS; COPPER; ALDEHYDE; ACTIVATION; ALLENES;
D O I
10.1039/c3ob41878b
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A simple, efficient and highly functional group compatible method for the synthesis of propargylamines from terminal alkynes, dichloromethane and tertiary amines using silver catalysts has been developed.
引用
收藏
页码:247 / 250
页数:4
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