Enantioresolution and absolute stereochemistry of o-substituted diphenylmethanols

被引:0
|
作者
Kuwahara, S
Watanabe, M
Harada, N
Koizumi, M
Ohkuma, T
机构
[1] Tohoku Univ, Inst Chem React Sci, Sendai, Miyagi 9808577, Japan
[2] Nagoya Univ, Grad Sch Sci, Dept Chem, Nagoya, Aichi 4648602, Japan
来源
ENANTIOMER | 2000年 / 5卷 / 01期
关键词
o-substituted diphenylmethanols; chiral dichlorophthalic acid amide; enantioresolution; HPLC separation; X-ray crystallography; absolute configuration; CD spectra;
D O I
暂无
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
o-Substituted diphenylmethanols were enantioresolved by the method of chiral dichlorophthalic acid amide, yielding enantiopure alcohols. Their absolute configurations were unambiguously determined by X-ray crystallography of chiral dichlorophthalate esters.
引用
收藏
页码:109 / 114
页数:6
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