Synthesis of D-glucose-based azacrown ethers with phosphonoalkyl side chain and their application to enantioselective reaction.

被引：0
|
作者：
Novák, T
Bakó, P
Pete, B
Keglevich, G
Ludányi, K
Töke, L
机构：
[1] Budapesti Muszaki & Gazdasagtudomanyi Egyetem, Szerves Kemiai Technol Tanszek, H-1521 Budapest, Hungary
[2] Hungarian Acad Sci, Kozponti Kemiai Kutato Kozpont, H-1525 Budapest, Hungary
[3] Budapesti Muszaki & Gazdasagtudomanyi Egyetem, MTA, Szerves Kemiai Technol Tanszeki Kutatocsoport, H-1521 Budapest, Hungary
来源：
MAGYAR KEMIAI FOLYOIRAT | 2000年 / 106卷 / 04期
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D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Chiral a-D-glucose-based monoaza-15-crown-5 ethers with phosphonoalkyl side chain (5a-e) have been synthesised. The substituent at the nitrogen atom had a major influence on the cation binding ability of the azacrown. The new lariat ethers (5a-e) showed significant asymmetic induction as phase transfer catalysts in the Michael addition of 2-nitropropane to chalcone.
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页码：171 / 176
页数：6
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