New Noncentrosymmetric Material - [N(CH3)4]ZnCl3: Polar Chains of Aligned ZnCl4 Tetrahedra

被引：55

作者：

Choi, Myung-Ho ^{[1
]}

Kim, Sang-Hwan ^{[2
]}

Chang, Hong-Young ^{[2
]}

Halasyamani, P. Shiv ^{[2
]}

Ok, Kang Min ^{[1
]}

机构：

[1] Chung Ang Univ, Dept Chem, Seoul 156756, South Korea

[2] Univ Houston, Dept Chem, Houston, TX 77204 USA

来源：

INORGANIC CHEMISTRY | 2009年 / 48卷 / 17期

关键词：

2ND-HARMONIC GENERATING PROPERTIES; BOND-VALENCE PARAMETERS; CRYSTAL-STRUCTURE; AMMONIUM TETRACHLOROZINCATE; CENTER DISTORTION; ZINC-CHLORIDE; OXIDES; ANION; STEREOCHEMISTRY; SOLIDS;

D O I：

10.1021/ic901064q

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new organically templated noncentrosymmetric polar zinc chloride, [N(CH3)(4)]ZnCl3, has been synthesized hydrothermally, and the structure was determined by single crystal X-ray diffraction. The reported material exhibits a unidimensional crystal structure consisting of chains of anionic ZnCl4 tetrahedra that are separated by [N(CH3)(4)](+) cations. Second-harmonic generation (SHG) measurement on the noncentrosymmetric [N(CH3)(4)]ZnCl3, using 1064 nm radiation, indicate the material has a SHG efficiency of approximately 15 x alpha-SiO2. Additional SHG measurements indicate the material is nonphase-matchable (type 1). In addition, converse piezoelectric measurements revealed d(33) values of 10 pm/V. Thermogravimetric analysis, UV-vis diffuse reflectance, and infrared spectroscopy were also performed, as were electronic structure calculations.. Crystal data: [N(CH3)(4)]ZnCl3, orthorhombic, space group Pmc2(1) (No. 26), with a = 7.2350(14) angstrom, b = 8.8210(18) angstrom, c = 15.303(3) angstrom, V = 976.6(3) angstrom(3), and Z = 4.

引用

页码：8376 / 8382

页数：7

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