SYNTHESIS OF THREE NEW VIC-DIOXIMES AND THEIR NICKEL(II) AND COPPER(II) COMPLEXES

被引：0

作者：

Guler, Ersin ^{[1
]}

机构：

[1] Selcuk Univ, Fac Arts & Sci, Dept Chem, TR-42075 Konya, Turkey

来源：

JOURNAL OF THE CHILEAN CHEMICAL SOCIETY | 2009年 / 54卷 / 02期

关键词：

Copper(II); Ligands; Nickel(II); Oximes; vic-dioximes; TRANSITION-METAL COMPLEXES; P-CHLOROPHENYLGLYOXIME; COBALT(II); PALLADIUM(II); CADMIUM(II); URANYL(VI);

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this study, anti-1-acetyl-1-cyclohexenylchloroglyoxime (C(8)H(11)ClN(2)O(2)) has been synthesized by chlorination of anti-1-acetyl-1-cyclohexenylchloroglyoxime. As a result of the reaction of C(8)H(11)ClN(2)O(2) with aryl- or arylalkylamines in ethanol between -10 degrees C and -15 degrees C, unsymmetrical vic-dioximes were obtained and the obtained products were named as: anilino-1-acetyl-1-cyclohexeneglyoxime (C(14)H(17)N(3)O(2)), bezylamino-1-acetyl-1-cyclohexeneglyoxime (C(15)H(19)N(3)O(2)), p-toluidino-1-acetyl-1-cylcohexeneglyoxime (C(15)H(19)N(3)O(2)) respectively. Their transition metal complexes have been synthesized. The form of the obtained Ni(II) and Cu(II) complexes were found as square-planer as it is known usually. (1)H n.m.r., conductivity measurements, magnetic properties, i.r spectra and elemental analyses data of ligands and complexes are given. In addition to this, thermal characterizations of the ligands and their complexes have been investigated.

引用

页码：163 / 167

页数：5

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