New magnetic frameworks of [(CuF2(H2O)2)x(pyz)]

被引：20

作者：

Lanza, A. ^{[1
,2
]}

Fiolka, C. ^{[1
]}

Fisch, M. ^{[1
,2
]}

Casati, N. ^{[2
]}

Skoulatos, M. ^{[3
]}

Rueegg, C. ^{[3
,4
]}

Kraemer, K. W. ^{[1
]}

Macchi, Piero ^{[1
]}

机构：

[1] Univ Bern, Dept Chem & Biochem, CH-3012 Bern, Switzerland

[2] Paul Scherrer Inst, Swiss Light Source, CH-5232 Villigen, Switzerland

[3] Paul Scherrer Inst, Lab Neutron Scattering & Imaging, CH-5232 Villigen, Switzerland

[4] Univ Geneva, DPMC MaNEP, CH-1211 Geneva, Switzerland

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 93期

基金：

瑞士国家科学基金会;

关键词：

CUPRIC FLUORIDE DIHYDRATE; CRYSTAL-STRUCTURE; LIGANDS;

D O I：

10.1039/c4cc06696k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Pressure-driven orbital reordering in the quantum magnet [CuF2(H2O)(2)(pyz)], (pyz = pyrazine), dramatically affects its magnetic exchange interactions. The crystal chemistry of this system is enriched with a new phase above 3 GPa, surprisingly concomitant with other polymorphs. Moreover, we discovered an unprecedented compound with a different stoichiometry, [(CuF2(H2O)(2))(2)(pyz)], featuring magnetic bi-layers.

引用

页码：14504 / 14507

页数：4

共 50 条

[31] Pressure-Induced Local Structure Distortions in Cu(pyz)F2(H2O)2
Musfeldt, J. L.
Liu, Z.
Li, S.
Kang, J.
Lee, C.
Jena, P.
Manson, J. L.
Schlueter, J. A.
Carr, G. L.
Whangbo, M. -H.
INORGANIC CHEMISTRY, 2011, 50 (13) : 6347 - 6352
[32] MONOCRYSTALLINE LAMELLARY GROWTH OF CUPROUS FLUORIDE CUF2
GILLARDE.J
CHARPIN, P
BULLETIN DE LA SOCIETE FRANCAISE MINERALOGIE ET DE CRISTALLOGRAPHIE, 1967, 90 (03): : 409 - &
[33] MAGNETIC STATE OF COBR2 . 6[(1 - X)H2O . XD2O]
HIJMANS, JPA
DEJONGE, WJM
VANDERLE.P
STEENLAND, MJ
PHYSICA, 1973, 69 (01): : 76 - 86
[34] The water dimer reaction OH + (H2O)2 → (H2O)-OH + H2O
Gao, Aifang
Li, Guoliang
Peng, Bin
Xie, Yaoming
Schaefer, Henry F., III
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2017, 19 (28) : 18279 - 18287
[35] SORPTION OF IONS OF ALKALI-METALS, COPPER (II), AND SILVER (I) FROM MEF(CUF2)-NAF(KF)-H2O SOLUTIONS BY KU-2X8 CATION-EXCHANGE RESIN
PAKHOLKOV, VS
ZELENKOV, BN
JOURNAL OF APPLIED CHEMISTRY OF THE USSR, 1974, 47 (09): : 2002 - 2004
[36] Alkynylation of cyclopropyl trifluoromethyl ketone catalyzed by CuF2•2H2O/4,7-diphenyl-1,10-phenanthroline
Liu, Xiao-Dong
Ma, Hai-Yan
Xing, Chun-Hui
Lu, Long
TETRAHEDRON LETTERS, 2017, 58 (16) : 1564 - 1567
[37] Crystal structure and magnetic behaviour of a new lanthanide acetate Gd(HF2CCOO)3(H2O)2-•H2O in comparison to Gd(H3CCOO)3(H2O)2•2H2O
Rohde, A
Hatscher, ST
Urland, W
JOURNAL OF ALLOYS AND COMPOUNDS, 2004, 374 (1-2) : 137 - 141
[38] Supramolecular 2D structure of [Co(2-Me-Pyz)2(H2O)4](NO3)2
Kokunov, Yu. V.
Gorbunova, Yu. E.
Kovalev, V. V.
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2009, 35 (09) : 643 - 647
[39] Supramolecular 2D structure of [Co(2-Me-Pyz)2(H2O)4](NO3)2
Yu. V. Kokunov
Yu. E. Gorbunova
V. V. Kovalev
Russian Journal of Coordination Chemistry, 2009, 35 : 643 - 647
[40] X-ray powder diffraction and IR study of NaMg(H2O)2[BP2O8]•H2O and NH4Mg(H2O)2[BP2O8]•H2O
Baykal, A
Kizilyalli, M
Kniep, R
JOURNAL OF MATERIALS SCIENCE, 2000, 35 (18) : 4621 - 4626

← 1 2 3 4 5 →