Two 1D Ladderlike Heterometallic Zinc(II) Coordination Polymers: Syntheses, Crystal Structures, and Fluorescence Properties

被引：2

作者：

Zheng, Yan-Feng ^{[1
]}

Sun, Ya-Qiu ^{[1
]}

Liu, Xiao-Xu ^{[1
]}

Xu, Yan-Yan ^{[1
]}

Gao, Dong-Zhao ^{[1
]}

Zhang, Guo-Ying ^{[1
]}

机构：

[1] Tianjin Normal Univ, Tianjin Key Lab Struct & Performance Funct Mol, Key Lab Inorgan Organ Hybrid Funct Mat Chem, Minist Educ,Coll Chem, Tianjin 300387, Peoples R China

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2014年 / 640卷 / 11期

基金：

中国国家自然科学基金;

关键词：

Macrocyclic oxamide complexes; Zinc; Crystal structure; Fluorescence; Heterometallic coordination polymers; METAL-ORGANIC FRAMEWORKS; MAGNETIC-PROPERTIES; HETERONUCLEAR COMPLEXES; MACROCYCLIC OXAMIDE; LIGANDS; AZIDO; 3D; CU; CU(PYAC)(2); CLUSTERS;

D O I：

10.1002/zaac.201400162

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two coordination polymers [Zn-2(ipt)(2)(CuL)(2)(H2O)] (1) and [Zn-2(ipt)(2)(NiL)(2)(H2O)] (2) (ML, H2L = 2,3-dioxo-5,6,14,15-dibenzo-1,4,8,12-tetraazacyclo-pentadeca-7,13-dien; H(2)ipt = isophthalic acid) were synthesized by solvothermal methods and characterized by single-crystal X-ray diffraction. Complexes 1 and 2 exhibit ladderlike chains, consisting of Zn4Cu4 and Zn4Ni4 units, respectively, which are connected via oxamide and isophthalate. These chains are further interlinked by hydrogen bonds resulting in a 2D supramolecular architecture. The fluorescence properties of compounds 1 and 2 are also discussed.

引用

页码：2232 / 2237

页数：6

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