Olive oil from the 79 AD Vesuvius eruption stored at the Naples National Archaeological Museum (Italy)

被引：6

作者：

Sacchi, Raffaele ^{[1
]}

Cutignano, Adele ^{[2
]}

Picariello, Gianluca ^{[3
]}

Paduano, Antonello ^{[4
]}

Genovese, Alessandro ^{[1
]}

Siano, Francesco ^{[3
]}

Nuzzo, Genoveffa ^{[2
]}

Caira, Simonetta ^{[5
]}

Lubritto, Carmine ^{[6
]}

Ricci, Paola ^{[6
]}

D'Auria, Alessia ^{[1
]}

Di Pasquale, Gaetano ^{[1
]}

Motta, Andrea ^{[2
]}

Addeo, Francesco ^{[1
]}

机构：

[1] Univ Naples Federico II, Unit Food Sci & Technol, Dept Agr Sci, Via Univ 100, I-80055 Naples, Italy

[2] ICB CNR, Inst Biomol Chem, Natl Res Council, Via Campi Flegrei 34, I-80078 Naples, Italy

[3] ISA CNR, Natl Res Council, Inst Food Sci, Via Roma 64, I-83100 Avellino, Italy

[4] Univ Bari Aldo Moro, Dept Agr & Environm Sci, Via Orabona 4, I-70125 Bari, Italy

[5] ISPAAM CNR, Natl Res Council, Inst Anim Prod Syst Mediterranean Environm, Via Argine 1085, I-80147 Naples, Italy

[6] Univ Campania Luigi Vanvitelli, Dept Environm Biol & Pharmaceut Sci & Technol, Via Vivaldi 43, I-81100 Caserta, Italy

来源：

NPJ SCIENCE OF FOOD | 2020年 / 4卷 / 01期

关键词：

NUCLEAR-MAGNETIC-RESONANCE; FLIGHT MASS-SPECTROMETRY; ESTOLIDES; ACID; LIPIDS; H-1;

D O I：

10.1038/s41538-020-00077-w

中图分类号：

TS2 [食品工业];

学科分类号：

0832 ;

摘要：

Using a range of chromatographic, spectroscopic, and mass spectrometric analytical techniques, we characterized one of the "edible items" found at the Vesuvius archeological sites and guarded at the National Archaeological Museum of Naples (MANN) in Naples, Italy. We authenticated the specimen contained in a glass bottle (Mann-S1 sample) as originally olive oil and mapped the deep evolution throughout its 2000 years of storage. Triacylglycerols were completely hydrolyzed, while the resulting (hydroxy) fatty acids had partly condensed into rarely found estolides. A complex pattern of volatile compounds arose mainly from breakdown of oleic acid. With excellent approximation, radiocarbon dating placed the find at the time of the Plinian Mount Vesuvius eruption in 79 A.D., indicating that Mann-S1 is probably the oldest residue of olive oil in the world found in bulk amount (nearly 0.7L).

引用

页数：9

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