Synthesis and properties of a corrole with small and electron-withdrawing substitutents, 5,15-bis(trifluoromethyl)-10-penta-fluorophenylcorrole

被引：24

作者：

Goldschmidt, Ruth

Goldberg, Israel ^{[1
]}

Balazs, Yael

Gross, Zeev

机构：

[1] Tel Aviv Univ, Sch Chem, IL-69978 Tel Aviv, Israel

[2] Technion Israel Inst Technol, Dept Chem, IL-32000 Haifa, Israel

[3] Technion Israel Inst Technol, Inst Catalysis Sci & Technol, IL-32000 Haifa, Israel

来源：

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES | 2006年 / 10卷 / 02期

关键词：

corroles; X-ray crystallography; NMR; synthesis;

D O I：

10.1142/S1088424606000107

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Several methodologies for the synthesis of corroles that carry minimal-sized electron-withdrawing substituents at the meso-C atoms were investigated; of these the one based on dypyrromethane/aidehyde condensation was fruitful. The new corrole with one C6F5 and two CF3 groups, as well as its cobalt(III) complex, were fully characterized by spectroscopy and X-ray crystallography. Copyright (c) 2006 Society of Porphyrins & Phthalocyanines.

引用

页码：76 / 86

页数：11

共 22 条

[21] Synthesis, transient absorption, and transient resonance Raman spectroscopy of novel electron donor-acceptor complexes:: [5,15-bis[(4′-nitrophenyl)ethynyl]-10,20-diphenylporphinato]copper(II) and [5-[[4′-(dimethylamino)phenyl]ethynyl]-15-[(4"-nitrophenyl)ethynyl]-10,20-diphenyl-porphinato]copper(II)
LeCours, SM
Philips, CM
de Paula, JC
Therien, MJ
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (51) : 12578 - 12589
[22] 7-COORDINATION IN METAL-COMPLEXES OF QUINQUEDENTATE MACROCYCLIC LIGANDS .5. SYNTHESIS AND PROPERTIES OF PENTAGONAL-BIPYRAMIDAL AND PENTAGONAL-PYRAMIDAL MANGANESE(II) COMPLEXES AND CRYSTAL AND MOLECULAR-STRUCTURE OF (2,15-DIMETHYL-3,7,10,14,20-PENTA-AZABICYCLO-[14.3.1]EICOSA-1(20),2,14,16,18-PENTAENE)BIS(ISOTHIOCYANATO)MANGANESE(II)I
DREW, MGB
HAMIDBINOTHMAN, A
MCFALL, SG
MCLLROY, PDA
NELSON, SM
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1977, (05): : 438 - 446

← 1 2 3 →