Synthesis and properties of a corrole with small and electron-withdrawing substitutents, 5,15-bis(trifluoromethyl)-10-penta-fluorophenylcorrole

被引：24
|
作者：
Goldschmidt, Ruth
Goldberg, Israel [1 ]
Balazs, Yael
Gross, Zeev
机构：
[1] Tel Aviv Univ, Sch Chem, IL-69978 Tel Aviv, Israel
[2] Technion Israel Inst Technol, Dept Chem, IL-32000 Haifa, Israel
[3] Technion Israel Inst Technol, Inst Catalysis Sci & Technol, IL-32000 Haifa, Israel
来源：
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES | 2006年 / 10卷 / 02期
关键词：
corroles; X-ray crystallography; NMR; synthesis;
D O I：
10.1142/S1088424606000107
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Several methodologies for the synthesis of corroles that carry minimal-sized electron-withdrawing substituents at the meso-C atoms were investigated; of these the one based on dypyrromethane/aidehyde condensation was fruitful. The new corrole with one C6F5 and two CF3 groups, as well as its cobalt(III) complex, were fully characterized by spectroscopy and X-ray crystallography. Copyright (c) 2006 Society of Porphyrins & Phthalocyanines.
引用
收藏
页码：76 / 86
页数：11
相关论文
共 22 条
  • [1] Effect of Solvents on the Deprotonation Reaction of 10-(5-Iodovanillyl)-5,15-bis(pentaflourophenyl)corrole
    E. A. Venediktov
    E. Yu. Tulikova
    Russian Journal of Physical Chemistry A, 2021, 95 : 63 - 67
  • [2] Effect of Solvents on the Deprotonation Reaction of 10-(5-Iodovanillyl)-5,15-bis(pentaflourophenyl)corrole
    Venediktov, E. A.
    Tulikova, E. Yu.
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2021, 95 (01) : 63 - 67
  • [3] Photodynamic Therapy Activities of 10-(4-Formylphenyl)-5,15-bis(pentafluorophenyl)corrole and Its Gallium Complex
    Cheng, Fan
    Huang, Liting
    Wang, Huahua
    Liu, Yunjun
    Kandhadi, Jaipal
    Wang, Hui
    Ji, Liangnian
    Liu, Haiyang
    CHINESE JOURNAL OF CHEMISTRY, 2017, 35 (01) : 86 - 92
  • [4] Synthesis, photophysical, electrochemical, and electrochemiluminescent properties of 5,15-bis(9-anthracenyl)porphyrin derivatives
    Sooambar, Chloe
    Troiani, Vincent
    Bruno, Carlo
    Marcaccio, Massimo
    Paolucci, Francesco
    Listorti, Andrea
    Belbakra, Abdelhalim
    Armaroli, Nicola
    Magistrato, Alessandra
    De Zorzi, Rita
    Geremia, Silvano
    Bonifazi, Davide
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2009, 7 (11) : 2402 - 2413
  • [5] Photodynamic Antitumor Activity of 5,15-Bis(perfluorophenyl)-10-(4-carboxyphenyl)corrole and its Gallium(III) and Phosphorus(V) Complexes
    Cen, Jing-He
    Wan, Bei
    Zhao, Yue
    Li, Meng-Yuan
    Liao, Yu-Hui
    Liu, Hai-Yang
    CHEMPLUSCHEM, 2022, 87 (07):
  • [6] SYNTHESIS, SPECTROSCOPY, AND STRUCTURAL STUDIES OF METAL-COMPLEXES OF 5,15-BIS(ARYLETHYNYL)-10,20-DIPHENYLPORPHYRINS
    LECOURS, SM
    DIMAGNO, SM
    THERIEN, MJ
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1994, 208 : 491 - INOR
  • [7] 5,15-Bis(pentafluorophenyl)-10,20-bis(2',5'-dibromo-3'-thienyl)porphyrin building block for the synthesis of aromatic polyethers
    Vainer, A. Ya.
    Dyumaev, K. M.
    Dragunskaya, R. M.
    Bel'skii, T. D.
    Golubeva, O. A.
    Taritskaya, Sh. I.
    DOKLADY CHEMISTRY, 2015, 461 : 70 - 74
  • [8] 5,15-Bis(pentafluorophenyl)-10,20-bis(2′,5′-dibromo-3′-thienyl)porphyrin building block for the synthesis of aromatic polyethers
    A. Ya. Vainer
    K. M. Dyumaev
    R. M. Dragunskaya
    T. D. Bel’skii
    O. A. Golubeva
    Sh. I. Taritskaya
    Doklady Chemistry, 2015, 461 : 70 - 74
  • [9] Synthesis of metal (Ga, Co and Fe) 5,15-bis(pentafluorophenyl)-10-ethox-ycarbonylcorrole and their electrocatalytic hydrogen evolution activity
    Peng, Wei-Yu
    Lan, Jian
    Zhu, Zheng-Mei
    Si, Li-Ping
    Zhang, Hao
    Zhan, Shu-Zhong
    Liu, Hai-Yang
    INORGANIC CHEMISTRY COMMUNICATIONS, 2022, 140
  • [10] Synthesis and versatile supramolecular self-assembly of the 5,15-bis(4-hydroxyphenyl)-10,20-bis(4-carboxyphenyl)porphyrin scaffold
    Vinodu, M
    Goldberg, I
    CRYSTENGCOMM, 2004, 6 : 215 - 220
123