Synthesis and characterization of organotin(IV) complexes of p-phenylphenol

被引:0
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作者
Sharma, N [1 ]
Pathania, SS [1 ]
Archana [1 ]
Bhatt, SS [1 ]
Chaudhry, SC [1 ]
机构
[1] Himachal Pradesh Univ, Dept Chem, Shimla 171005, Himachal Prades, India
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中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The di- and tri-organotin(IV) complexes with the composition R2SnCl2-n(OC6H4Ph-p)(n) and (C6H5)(3)Sn(OC6H4Ph-p) (R = n-C4H9 and Me; n = 1 and 2) have been synthesized by the reaction of dialkyl and triphenyltin(IV) chlorides with p-phenylphenol in the presence of diethylamine in diethylether at room temperature. The complexes have been characterized by their analytical data and IR and H-1 NMR spectra. Thermal behaviour of the complexes has been studied by TGA/ DTA methods. Lewis acid character of the complexes has been established by reacting them with nitrogenous bases such as 2,2'-bipyridyl, 1,10- phenanthroline and 2,2'- dipyridylamine.
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页码:1672 / 1675
页数:4
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