J-aggregate electroluminescence in polymer matrices

被引:9
|
作者
Mal'tsev, EI [1 ]
Lypenko, DA [1 ]
Shapiro, BI [1 ]
Milburn, GHW [1 ]
Wright, J [1 ]
Hendriksen, A [1 ]
Berendyaev, VI [1 ]
Kotov, BV [1 ]
Vannikov, AV [1 ]
机构
[1] Russian Acad Sci, AN Frumkin Electrochem Inst, Moscow 117071, Russia
关键词
polymer LEDs; electroactive polymers; nanocrystalline phase; polymer composites;
D O I
10.1117/12.372716
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Cyanine dye electroluminescence was observed in single layer light-emitting diodes based on electron-hole conducting polymers, The appearance of light emission in the visible range depended on the reduction/oxidation potentials of the dyes used. In polymer systems, the electroluminescence of cyanine dye J-aggregate nanocrystalline phase was detected for the first time. J-aggregate/polymer composites exhibiting intense absorption band with a maximum in the red range were developed on the base of polyimides and a copolymer coformed from phenylacetylene and 4-methylcoumarin-4-pentynoate doped with the dye luminophores. Efficient electrolumunescence was revealed in these systems. It was demostrated that J-aggregates play an active role in charge carrier transport in the composite materials. In particular, anthracene-containing polyimides exhibiting electron-hole transport appeared to be appropriate media for the generation of J-aggregate electroluminescence.
引用
收藏
页码:246 / 255
页数:10
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