Titanocene and zirconocene complexes of a phosphorus analog of an Arduengo's carbene:: Application in the synthesis of 1,3-diphosphafulvenes

被引：20

作者：

Cantat, T ^{[1
]}

Mézailles, N ^{[1
]}

Maigrot, N ^{[1
]}

Ricard, L ^{[1
]}

Le Floch, P ^{[1
]}

机构：

[1] Ecole Polytech, CNRS, UMR 7653, Dept Chim,Lab Heteroelements & Coordinat, F-91128 Palaiseau, France

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 11期

关键词：

D O I：

10.1039/b403436h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Titanocene and zirconocene carbene complexes of a phosphorus equivalent of an Arduengo's carbene have been synthesized in the coordination sphere of titanocene and zirconocene and exhibit a nucleophilic character which has been exploited in the synthesis of 1,3-diphosphafulvenes.

引用

页码：1274 / 1275

页数：2

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