Charge disproportionation in the metallic state of α-(BEDT-TTF)2|3

被引:37
|
作者
Moroto, S [1 ]
Hiraki, K
Takano, Y
Kubo, Y
Takahashi, T
Yamamoto, HM
Nakamura, T
机构
[1] Gakushuin Univ, Dept Phys, Toshima Ku, Tokyo 1718588, Japan
[2] RIKEN, Inst Phys & Chem Res, Wako, Saitama 3510198, Japan
[3] Inst Mol Sci, Okazaki, Aichi 4448585, Japan
来源
JOURNAL DE PHYSIQUE IV | 2004年 / 114卷
关键词
C-13-NMR; charge dissproportination;
D O I
10.1051/jp4:2004114077
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
C-13-NMR measurements have been carried out on the quasi two-dimensional organic conductor, alpha-(BEDT-TTF)(2)I-3. We measured the angular dependence of C-13-NMR spectrum at several temperatures above metal-insulator transition temperature, 135 K (=T-MI). We found that charge (spin) disproportionation already exists in the metallic state and gradually develops as temperature approaches to T-MI.
引用
收藏
页码:339 / 340
页数:2
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