Evidence for equilibrium between N-substituted 3-phosphorylidenepyrrolidine-2,5-diones and N-substituted maleimides and phosphines:: Thermal instability of the N-substituted phosphoranes

被引：3

作者：

Koszytkowska-Stawinska, M ^{[1
]}

Sas, W ^{[1
]}

机构：

[1] Warsaw Univ Technol, Fac Chem, PL-00664 Warsaw, Poland

来源：

JOURNAL OF CHEMICAL RESEARCH-S | 1999年 / 12期

关键词：

D O I：

10.1039/a904433g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The formation of N-substituted 3-phosphorylidenepyrrolidine-2,5-diones from N-substituted maleimides and phosphines is reversible and at elevated temperature the phosphoranes behave as a source of maleimide derivatives which give the corresponding cycloadducts with nitrones and 1,3-dienes; a consequence of this equilibrium is the thermal instability of the ylides.

引用

页码：694 / 695A

页数：5

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