Evidence for equilibrium between N-substituted 3-phosphorylidenepyrrolidine-2,5-diones and N-substituted maleimides and phosphines:: Thermal instability of the N-substituted phosphoranes

被引：3
|
作者：
Koszytkowska-Stawinska, M [1 ]
Sas, W [1 ]
机构：
[1] Warsaw Univ Technol, Fac Chem, PL-00664 Warsaw, Poland
来源：
JOURNAL OF CHEMICAL RESEARCH-S | 1999年 / 12期
关键词：
D O I：
10.1039/a904433g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The formation of N-substituted 3-phosphorylidenepyrrolidine-2,5-diones from N-substituted maleimides and phosphines is reversible and at elevated temperature the phosphoranes behave as a source of maleimide derivatives which give the corresponding cycloadducts with nitrones and 1,3-dienes; a consequence of this equilibrium is the thermal instability of the ylides.
引用
收藏
页码：694 / 695A
页数：5
相关论文
共 50 条
  • [1] THE ISOMERISM OF N-SUBSTITUTED MALEIMIDES
    RODERICK, WR
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1957, 79 (07) : 1710 - 1712
  • [2] THE CONDENSATION OF N-SUBSTITUTED MALEIMIDES WITH THIOUREAS
    MARRIAN, DH
    JOURNAL OF THE CHEMICAL SOCIETY, 1949, (JUL): : 1797 - 1799
  • [3] A facile synthesis of N-substituted maleimides
    Deshpande, Sunita R.
    Maybhate, Shailaja P.
    Likhite, Anjali P.
    Chaudhary, Preeti M.
    INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 2010, 49 (04): : 487 - 488
  • [4] A PRACTICAL SYNTHESIS OF N-SUBSTITUTED MALEIMIDES
    BRAISH, TF
    FOX, DE
    SYNLETT, 1992, (12) : 979 - 980
  • [5] COPOLYMERIZATION OF ACRYLONITRILE WITH N-SUBSTITUTED MALEIMIDES
    SABAA, MW
    MIKHAEL, MG
    YASSIN, AA
    ELSABEE, MZ
    ANGEWANDTE MAKROMOLEKULARE CHEMIE, 1986, 139 : 95 - 112
  • [6] N-SUBSTITUTED MALEIMIDES AS THERMAL STABILIZERS FOR RIGID POLYVINYLCHLORIDE
    SABAA, MW
    MIKHAEL, MG
    MOHAMED, NA
    YASSIN, AA
    ANGEWANDTE MAKROMOLEKULARE CHEMIE, 1989, 168 : 23 - 35
  • [7] THE REACTION OF ENONES WITH N-SUBSTITUTED HYDRAZINES AND N-SUBSTITUTED UREAS
    KASHIMA, C
    YOSHIWARA, N
    HETEROCYCLES, 1985, 23 (01) : 171 - 171
  • [8] POLAROGRAPHIC AND BIOLOGIC ACTIVITIES OF N-SUBSTITUTED MALEIMIDES
    MUIR, RM
    PROCEEDINGS OF THE SOCIETY FOR EXPERIMENTAL BIOLOGY AND MEDICINE, 1959, 102 (01): : 157 - 160
  • [9] REACTION OF GRIGNARD REAGENTS WITH N-SUBSTITUTED MALEIMIDES
    QUEEN, A
    REIPAS, A
    JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC, 1967, (04): : 245 - &
  • [10] POLYMERIZATION OF N-SUBSTITUTED MALEIMIDES INITIATED BY THIOPHENOL
    TAKEISHI, M
    ARIMORI, S
    IWASAKI, N
    SEKIYA, K
    SATO, R
    POLYMER JOURNAL, 1992, 24 (04) : 365 - 373
12345