ANALYSIS OF SOLVENTS PROPERTIES INFLUENCE ON THE KINETICS OF SOME HOMOLYTIC REACTIONS

被引：0
|
作者：
Makitra, R. G. [1 ]
Midyana, G. G. [1 ]
Bazylyak, L. I. [1 ]
Zaikov, G. E. [2 ]
机构：
[1] Natl Acad Sci Ukraine, Dept Phys Chem Combustible Minerals, LM Lytvynenko Inst Phys Organ Chem & Coal Chem, UA-79060 Lvov, Ukraine
[2] Russian Acad Sci, NM Emmanuel Inst Biochem Phys, Moscow 119991, Russia
来源：
OXIDATION COMMUNICATIONS | 2009年 / 32卷 / 02期
关键词：
peresters; medium influence; kinetics; DECOMPOSITION;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The rate constants of the non-inhibited decomposition of peracids ethers in different solvents can be generalised by means of the multiple equations of the Koppel-Palm type supplemented with the factors taking into account also the structural properties of medium, namely, self-association and molar volume of the solvents. As a rule, prevailing factor is the electrophilic solvation of the peroxide upon its carboxy group.
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页码：245 / 260
页数：16
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