CRYSTALLOGRAPHIC ANALYSIS OF THE GARNET STRUCTURE TYPE: SYMMETRY IN THE STRUCTURAL ANATOMY

被引：5
|
作者：
Borisov, S., V [1 ]
Magarill, S. A. [1 ]
Pervukhina, N., V [1 ]
机构：
[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk, Russia
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2018年 / 59卷 / 02期
关键词：
crystallographic stability; crystallographic analysis; cation sublattices; coherent assembly; garnet structure type; beta-W structure; menezesite;
D O I：
10.1134/S0022476618020154
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The crystallographic analysis of the garnet structure type (Al2Ca3(SiO4)(3), Ia3d symmetry) establishes the determining role of the [AlCa6Si6] cation group with the local symmetry 3 in the structure formation. The glide planes of three directions coherently assemble these groups. High structural stability (three not symmetry-fixed coordinates per 80 atoms, the fundamental volume V* similar to 17 angstrom(3)) promotes the occurrence of various atomic compositions in it. The relation with the beta-W structure type and the structure of menezesite mineral is shown.
引用
收藏
页码：365 / +
页数：6
相关论文
共 50 条
  • [41] ANALYSIS OF CHAIN FOLDING IN CRYSTALLINE ISOTACTIC POLYPROPYLENE - THE IMPLICATIONS OF TACTICITY AND CRYSTALLOGRAPHIC SYMMETRY
    PETRACCONE, V
    PIROZZI, B
    MEILLE, SV
    POLYMER, 1986, 27 (11) : 1665 - 1668
  • [42] Structure and crystallographic texture of a metallic meteorite of octahedrite type (Gibeon)
    Sevillano, JG
    García-Rosales, C
    Echeberria, JJ
    Zubillaga, C
    BOLETIN DE LA SOCIEDAD ESPANOLA DE CERAMICA Y VIDRIO, 2000, 39 (03): : 313 - 318
  • [43] SYMMETRY CONCEPTS IN THE STRUCTURAL ANALYSIS OF DEFORMED ROCKS
    PATERSON, MS
    WEISS, LE
    GEOLOGICAL SOCIETY OF AMERICA BULLETIN, 1961, 72 (06) : 841 - 882
  • [44] SYMMETRY ANALYSIS OF ANOMALOUS HYPERFINE STRUCTURE
    SHUEY, RT
    ZELLER, HR
    HELVETICA PHYSICA ACTA, 1967, 40 (04): : 325 - &
  • [45] A Fourier analysis of symmetry in protein structure
    Taylor, WR
    Heringa, J
    Baud, F
    Flores, TP
    PROTEIN ENGINEERING, 2002, 15 (02): : 79 - 89
  • [46] Tin coordination compounds: Classification and analysis of crystallographic and structural data
    Holloway, CE
    Melnik, M
    MAIN GROUP METAL CHEMISTRY, 1998, 21 (7-8): : 371 - 488
  • [47] MERCURY ORGANOMETALLIC COMPOUNDS - CLASSIFICATION AND ANALYSIS OF CRYSTALLOGRAPHIC AND STRUCTURAL DATA
    HOLLOWAY, CE
    MELNIK, M
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 495 (1-2) : 1 - 31
  • [48] Germanium coordination compounds: Classification and analysis of crystallographic and structural data
    Holloway, CE
    Melnik, M
    MAIN GROUP METAL CHEMISTRY, 2001, 24 (10): : 681 - 726
  • [49] Symmetry and structural relationships among ABW-type materials
    Kahlenberg, V
    Fischer, RX
    Baur, WH
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 2001, 216 (09): : 489 - 494
  • [50] ZINC(II) COMPOUNDS: CLASSIFICATION AND ANALYSIS OF CRYSTALLOGRAPHIC AND STRUCTURAL DATA
    Melnik, Milan
    Gyoeryova, Katarina
    Skorsepa, Jan
    Holloway, Clive E.
    JOURNAL OF COORDINATION CHEMISTRY, 1995, 35 (3-4) : 179 - 279
12345