CRYSTALLOGRAPHIC ANALYSIS OF THE GARNET STRUCTURE TYPE: SYMMETRY IN THE STRUCTURAL ANATOMY

被引：5
|
作者：
Borisov, S., V [1 ]
Magarill, S. A. [1 ]
Pervukhina, N., V [1 ]
机构：
[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk, Russia
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2018年 / 59卷 / 02期
关键词：
crystallographic stability; crystallographic analysis; cation sublattices; coherent assembly; garnet structure type; beta-W structure; menezesite;
D O I：
10.1134/S0022476618020154
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The crystallographic analysis of the garnet structure type (Al2Ca3(SiO4)(3), Ia3d symmetry) establishes the determining role of the [AlCa6Si6] cation group with the local symmetry 3 in the structure formation. The glide planes of three directions coherently assemble these groups. High structural stability (three not symmetry-fixed coordinates per 80 atoms, the fundamental volume V* similar to 17 angstrom(3)) promotes the occurrence of various atomic compositions in it. The relation with the beta-W structure type and the structure of menezesite mineral is shown.
引用
收藏
页码：365 / +
页数：6
相关论文
共 50 条
  • [1] Crystallographic Analysis of the Garnet Structure Type: Symmetry in the Structural Anatomy
    S. V. Borisov
    S. A. Magarill
    N. V. Pervukhina
    Journal of Structural Chemistry, 2018, 59 : 365 - 370
  • [2] CRYSTAL SYMMETRY OF THE GARNET STRUCTURE
    CHENAVAS, J
    JOUBERT, JC
    MAREZIO, M
    FERRAND, B
    JOURNAL OF THE LESS-COMMON METALS, 1978, 62 (NOV-): : 373 - 380
  • [3] Crystallographic symmetry and magnetic structure of CoO
    Jauch, W
    Reehuis, M
    Bleif, HJ
    Kubanek, F
    Pattison, R
    PHYSICAL REVIEW B, 2001, 64 (05):
  • [4] CRYSTAL CHEMICAL AND CRYSTALLOGRAPHIC PROPERTIES OF COMPOUNDS WITH GARNET OR HYDROGARNET STRUCTURE
    BASSO, R
    NEUES JAHRBUCH FUR MINERALOGIE-MONATSHEFTE, 1985, (03): : 108 - 114
  • [5] CRYSTALLOGRAPHIC AND THEORETIC-GROUP ANALYSIS OF IMPURITY-ION PAIRS IN CRYSTALS OF GARNET STRUCTURE
    NAISH, VE
    MEN, BA
    MEN, AN
    OPTIKA I SPEKTROSKOPIYA, 1975, 39 (06): : 1126 - 1135
  • [6] CRYSTALLOGRAPHIC AND SPECTROSCOPIC STUDIES OF EUROPIUM TRIVALENT DOPED GARNET TYPE GERMANATES
    PELLE, F
    DENIS, JP
    BLANZAT, B
    PANNEL, C
    MATERIALS RESEARCH BULLETIN, 1977, 12 (05) : 511 - 517
  • [7] The Analysis of Crystallographic Symmetry Types in Finite Groups
    Sani, Atikah Mohd
    Sarmin, Nor Haniza
    Adam, Nooraishikin
    Zamri, Siti Norziahidayu Amzee
    PROCEEDINGS OF THE 3RD INTERNATIONAL CONFERENCE ON MATHEMATICAL SCIENCES, 2014, 1602 : 834 - 843
  • [8] Use of non-crystallographic symmetry in protein structure refinement
    Kleywegt, GJ
    ACTA CRYSTALLOGRAPHICA SECTION D-BIOLOGICAL CRYSTALLOGRAPHY, 1996, 52 : 842 - 857
  • [9] A LINEAR ANALYSIS OF NON-CRYSTALLOGRAPHIC SYMMETRY PROBLEM
    CROWTHER, RA
    ACTA CRYSTALLOGRAPHICA, 1967, 22 : 758 - &
  • [10] Dynamic electron scattering distinguishes dodecahedral and tetrahedral crystallographic sites in garnet structure
    Lábár, JL
    APPLIED PHYSICS LETTERS, 1999, 75 (01) : 70 - 72
12345