Physical solvent extraction of levulinic acid from dilute aqueous solution with 2-methyltetrahydrofuran

被引:14
|
作者
Laitinen, Antero T. [1 ]
Penttila, Karri J. T. [1 ]
Kaunisto, Juha M. [1 ]
机构
[1] VTT Tech Res Ctr Finland, FI-02044 Espoo, Finland
关键词
Extraction; levulinic acid; physical solvent; 2-methyltetrahydrofuran; REACTIVE EXTRACTION; FERMENTATION BROTH; RECOVERY; FRUCTOSE;
D O I
10.1080/01496395.2015.1105264
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The results of the present investigation reveal that 2-methyltetrahydrofuran is a potential solvent for the extraction of levulinic acid from dilute aqueous solution. This conclusion is based on the relatively high values of distribution coefficient K-d (1.3-1.6) measured for the system of levulinic acid - water - 2-methyltetrahydrofuran at temperatures 298.2 K, 313.2 K, and 328.2 K, as well as encouraging performance of the continuous counter current Kuhni column. The results give reason to believe, that 2-methyltetrahydrofuran can be considered for the extraction of other low molecular weight acids, such as formic or lactic acid, as well.
引用
收藏
页码:465 / 473
页数:9
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