The formation of polylectrolyte complexes (PECs) by the interaction between poly(dimethyldiallylammonium chloride) and native potato starch was investigated. PECs with optimal dye binding properties containing 0.015-0.02 mole cationic polymer/anhydroglucose residue were prepared. It was shown that the anionic (acid) dye was incorporated into PECs by electrostatic interaction with the free cationic groups of PECs. The principal role of the hydrophobicity of the PECs containing acid dye in their stability in water solutions was revealed. The precipitation occurred due to the minimum amount of free ionic groups.
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Tokyo Inst Technol, Dept Organ Mat & Macromol, Int Res Ctr Macromol Sci, Meguro Ku, Tokyo 1528552, JapanTokyo Inst Technol, Dept Organ Mat & Macromol, Int Res Ctr Macromol Sci, Meguro Ku, Tokyo 1528552, Japan
Ishizu, K
Toyoda, K
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Tokyo Inst Technol, Dept Organ Mat & Macromol, Int Res Ctr Macromol Sci, Meguro Ku, Tokyo 1528552, JapanTokyo Inst Technol, Dept Organ Mat & Macromol, Int Res Ctr Macromol Sci, Meguro Ku, Tokyo 1528552, Japan
Toyoda, K
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Furukawa, T
Sogabe, A
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Tokyo Inst Technol, Dept Organ Mat & Macromol, Int Res Ctr Macromol Sci, Meguro Ku, Tokyo 1528552, JapanTokyo Inst Technol, Dept Organ Mat & Macromol, Int Res Ctr Macromol Sci, Meguro Ku, Tokyo 1528552, Japan
机构:
E China Univ Sci & Technol, Dept Chem, State Key Lab Chem Engn, Shanghai 200237, Peoples R ChinaE China Univ Sci & Technol, Dept Chem, State Key Lab Chem Engn, Shanghai 200237, Peoples R China
Pi, YY
Shang, YZ
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E China Univ Sci & Technol, Dept Chem, State Key Lab Chem Engn, Shanghai 200237, Peoples R ChinaE China Univ Sci & Technol, Dept Chem, State Key Lab Chem Engn, Shanghai 200237, Peoples R China
Shang, YZ
Liu, HL
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E China Univ Sci & Technol, Dept Chem, State Key Lab Chem Engn, Shanghai 200237, Peoples R ChinaE China Univ Sci & Technol, Dept Chem, State Key Lab Chem Engn, Shanghai 200237, Peoples R China
Liu, HL
Hu, Y
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E China Univ Sci & Technol, Dept Chem, State Key Lab Chem Engn, Shanghai 200237, Peoples R ChinaE China Univ Sci & Technol, Dept Chem, State Key Lab Chem Engn, Shanghai 200237, Peoples R China