Benchtop flow-NMR for rapid online monitoring of RAFT and free radical polymerisation in batch and continuous reactors

被引：41

作者：

Knox, Stephen T. ^{[1
]}

Parkinson, Sam ^{[1
]}

Stone, Raphael ^{[1
]}

Warren, Nicholas J. ^{[1
]}

机构：

[1] Univ Leeds, Sch Chem & Proc Engn, Woodhouse Lane, Leeds LS2 9JT, W Yorkshire, England

来源：

POLYMER CHEMISTRY | 2019年 / 10卷 / 35期

基金：

英国工程与自然科学研究理事会;

关键词：

MULTIBLOCK COPOLYMERS; SPECTROSCOPY; KINETICS; SYSTEM;

D O I：

10.1039/c9py00982e

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A "Benchtop" NMR spectrometer is used for detailed monitoring of controlled and free radical polymerisations performed in batch and continuous reactors both offline and in real-time. This allows detailed kinetic analysis with unprecedented temporal resolution for reactions which reach near completion in under five minutes.

引用

页码：4774 / 4778

页数：5

共 22 条

[21] A benchtop NMR spectrometer as a tool for monitoring mesoscale continuous-flow organic synthesis: equipment interface and assessment in four organic transformations
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Leadbeater, Nicholas E.
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[22] Metal-Free Radical-Triggered Selenosulfonation of 1,7-Enynes for the Rapid Synthesis of 3,4-Dihydroquinolin-2(1H)-ones in Batch and Flow
Qiu, Jiang-Kai
Shan, Cheng
Wang, De-Cai
Wei, Ping
Jiang, Bo
Tu, Shu-Jiang
Li, Guigen
Guo, Kai
ADVANCED SYNTHESIS & CATALYSIS, 2017, 359 (24) : 4332 - 4339

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