Benchtop flow-NMR for rapid online monitoring of RAFT and free radical polymerisation in batch and continuous reactors

被引：41
|
作者：
Knox, Stephen T. [1 ]
Parkinson, Sam [1 ]
Stone, Raphael [1 ]
Warren, Nicholas J. [1 ]
机构：
[1] Univ Leeds, Sch Chem & Proc Engn, Woodhouse Lane, Leeds LS2 9JT, W Yorkshire, England
来源：
POLYMER CHEMISTRY | 2019年 / 10卷 / 35期
基金：
英国工程与自然科学研究理事会;
关键词：
MULTIBLOCK COPOLYMERS; SPECTROSCOPY; KINETICS; SYSTEM;
D O I：
10.1039/c9py00982e
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A "Benchtop" NMR spectrometer is used for detailed monitoring of controlled and free radical polymerisations performed in batch and continuous reactors both offline and in real-time. This allows detailed kinetic analysis with unprecedented temporal resolution for reactions which reach near completion in under five minutes.
引用
收藏
页码：4774 / 4778
页数：5
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