Heterogeneous relaxation patterns in supercooled liquids studied by solvation dynamics

We have measured the solvation dynamics of a dipolar supercooled liquid near its glass transition in a temperature range in which the average structural relaxation time varies more than four orders of magnitude. The analysis of the time dependent average emission energy and the inhomogeneous linewidth of the S-0 <--T-1(0-0) transition reveals that the orientation correlation decay pattern intrinsic in each relaxing unit is associated with a stretching exponent beta(intr) = 1.00 +/- 0.08 in the entire range T-g less than or equal to T less than or equal to T-g + 6 K. Our analysis also allows one to detect fluctuations in terms of the resulting apparent homogeneity within the long time tail of the decay. Even at times significantly exceeding the average structural relaxation lime, no sign of a transition towards purely exponential or otherwise homogeneous behavior could be observed. This implies that even at t approximate to 50[tau](KWW) the individual time constants remain correlated to their initial values at t = 0.