Adsorption mechanism of some bivalent heavy metal cations in solutions using montmorillonite

被引:0
|
作者
Xia, HP
Ke, JJ
机构
[1] TSING HUA UNIV,DEPT ENVIRONM ENGN,BEIJING 100084,PEOPLES R CHINA
[2] CHINESE ACAD SCI,INST CHEM MET,BEIJING,PEOPLES R CHINA
关键词
montmorillonite; INDO method; frontier orbital energies; isothermal adsorption; powder X-ray diffraction; heavy metal cations;
D O I
暂无
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
The frontier orbital energies of montmorillonite molecule and [Me(H2O)(6)](2+) (Me = Cu2+, Zn2+, Co2+ and Ni2+) were calculated by INDO method. Results showed that the chemical interaction between montmorillonite molecule and [CU(H2O)(6)](2+) or [Zn(H2O)(6)](2+) was possible. The experimental results of powder X-ray diffraction and isothermal adsorption supported the above-mentioned calculation results.
引用
收藏
页码:32 / 34
页数:3
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