Synthesis of new pyrrolidine nitroxide epoxides as versatile paramagnetic building blocks

被引:7
|
作者
Kálai, T
Sár, CP
Jekö, J
Hideg, K
机构
[1] Univ Pecs, Inst Organ & Med Chem, H-7643 Pecs, Hungary
[2] ICN Hungary, H-4440 Tiszavasvari, Hungary
基金
匈牙利科学研究基金会;
关键词
nitroxides; epoxides; spin labels; ring opening;
D O I
10.1016/S0040-4039(02)01911-1
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Pyrrolidine nitroxide epoxides were synthesized by oxidation of the corresponding alkene, diene and alpha,beta-unsaturated aldehyde with m-CPBA or H2O2 to provide new spin labels and paramagnetic synthons. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:8125 / 8127
页数:3
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