Ionic Liquids: The Synergistic Catalytic Effect in the Synthesis of Cyclic Carbonates

被引：71

作者：

Cheng, Weiguo ^{[1
]}

Su, Qian ^{[1
,2
]}

Wang, Jinquan ^{[1
]}

Sun, Jian ^{[1
]}

Ng, Flora T. T. ^{[3
]}

机构：

[1] Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing Key Lab Ion Liquids Clean Proc, Beijing 100190, Peoples R China

[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

[3] Univ Waterloo, Dept Chem Engn, Waterloo, ON N2L 3G1, Canada

来源：

CATALYSTS | 2013年 / 3卷 / 04期

关键词：

synergistic effect; ionic liquid; cyclic carbonates; carbon dioxide; CHEMICAL FIXATION; PROPYLENE CARBONATE; COUPLING REACTIONS; STYRENE CARBONATE; HIGHLY EFFICIENT; GREEN CHEMISTRY; SOLVENTLESS SYNTHESIS; MESOPOROUS SILICA; DIOXIDE; CO2;

D O I：

10.3390/catal3040878

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This review presents the synergistic effect in the catalytic system of ionic liquids (ILs) for the synthesis of cyclic carbonate from carbon dioxide and epoxide. The emphasis of this review is on three aspects: the catalytic system of metal-based ionic liquids, the catalytic system of hydrogen bond-promoted ionic liquids and supported ionic liquids. Metal and ionic liquids show a synergistic effect on the cycloaddition reactions of epoxides. The cations and anions of ionic liquids show a synergistic effect on the cycloaddition reactions. The functional groups in cations or supports combined with the anions have a synergistic effect on the cycloaddition reactions. Synergistic catalytic effects of ILs play an important role of promoting the cycloaddition reactions of epoxides. The design of catalytic system of ionic liquids will be possible if the synergistic effect on a molecular level is understood.

引用

页码：878 / 901

页数：24

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