Preparation, crystal structure, and electrical properties of thallium monosulfide in the vicinity of high-temperature phase transitions

被引：10
|
作者：
Aliev, V. P.
Gasimov, Sh. G.
Mammadov, T. G.
Mammadov, T. S.
Nadjafov, A. I.
Seyidov, MirHasan Yu.
机构：
[1] Azerbaijan Natl Acad Sci, Inst Phys, AZ-1143 Baku, Azerbaijan
[2] Gazi Univ, Dept Phys, TR-06500 Ankara, Turkey
[3] Gebze Inst Technol, Dept Phys, TR-41400 Kocaeli, Turkey
来源：
PHYSICS OF THE SOLID STATE | 2006年 / 48卷 / 12期
关键词：
D O I：
10.1134/S1063783406120134
中图分类号：
O469 [凝聚态物理学];
学科分类号：
070205 ;
摘要：
Single crystals of thallium monosulfide TIS with excess sulfur (4 at. %) are grown. The existence of monoclinic (of the TIGaSe2 type), tetragonal ordered (of the TIS type), and subtetragonal phases of thallium monosulfide is revealed using x-ray powder diffraction. The temperature dependences of the electrical conductivity and permittivity of thallium monosulfide single crystals indicate that, in the temperature range 401-411 K, these crystals undergo a phase transition to a state with superionic conduction.
引用
收藏
页码：2322 / 2327
页数：6
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