Enhanced performance of sulfone-based electrolytes at lithium ion battery electrodes, including the LiNi0.5Mn1.5O4 high voltage cathode

被引：78
|
作者：
Xue, Leigang [1 ]
Ueno, Kazuhide [1 ]
Lee, Seung-Yul [1 ]
Angell, C. Austen [1 ]
机构：
[1] Arizona State Univ, Dept Chem & Biochem, Tempe, AZ 85287 USA
来源：
JOURNAL OF POWER SOURCES | 2014年 / 262卷
关键词：
Lithium ion battery; Sulfone-based electrolytes; High voltage electrolyte; 99-100% coulombic efficiency at LNMO cathode; High capacity retention; LIQUIDS; LIBOB;
D O I：
10.1016/j.jpowsour.2014.03.099
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
In an extension of our previous studies of sulfone-containing electrolytes for lithium batteries, we report tests of sulfone-carbonate, and all-sulfone, electrolytes in a variety of anode and cathode half cells. While the all-sulfone electrolyte appears promising at the graphite anode in early cycles, it fails at the high voltage cathode and will not be further tested. On the other hand a sulfone-carbonate mixed solvent performs very well (97% capacity retention after 100 cycles with 99-100% coulomb efficiency) at the LiNi0.5M1.5O4 (LNMO) cathode, and also at the Li4Ti5O12 (LTO) anode, both of which are being developed for high power applications. Published by Elsevier B.V.
引用
收藏
页码：123 / 128
页数：6
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