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Synthesis, crystal structure and magnetic properties of a new three-dimensional porous framework:: [Gd2(BDA)3(DMF)2(H2O)4] • 2DMF

被引：12
|
作者：
Wu, Chuan-De [1 ]
机构：
[1] Zhejiang Univ, Dept Chem, Hangzhou 311027, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2006年 / 9卷 / 12期
关键词：
crystal structure; ferromagnetic interaction; functional group; porous framework; tether;
D O I：
10.1016/j.inoche.2006.07.040
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The open framework compound of [Gd-2(BDA)(3)(DMF)(2)(H2O)(4)]center dot 2DMF (1), prepared by heating GdCl3 with 2,2'-bipyridyl-4,4'-dicarboxylatic acid (BDA) in mixed solvent, is constructed from BDA linking up polymeric [GdO5(DMF)(H2O)(2)](n) tethers. The 1D channels are filled with coordinated and uncoordinated DMF molecules hydrogen bonding to terminal aqua ligands. The study of the temperature dependent magnetic susceptibilities revealed that there are ferromagnetic interactions between intra-chain Gd-III atoms and weak antiferromagnetic interactions between inter-chain Gd-III atoms. (C) 2006 Elsevier B.V. All rights reserved.
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收藏
页码：1223 / 1226
页数：4
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