NaBH4/charcoal:: A new synthetic method for mild and convenient reduction of nitroarenes

被引:53
|
作者
Zeynizadeh, Behzad [1 ]
Setamdideh, Davood [1 ]
机构
[1] Urmia Univ, Fac Sci, Dept Chem, Urmia 57159165, Iran
关键词
amines; charcoal; NaBH4; nitroarenes; reduction;
D O I
10.1080/00397910600764709
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
NaBH4 in the presence of charcoal (0.4 - 0.8 g) reduces varieties of nitro-arenes to their corresponding amines. Reduction reactions were carried out in a mixture of H2O-THF ( 1: 0.5 mL) at 50 - 60 degrees C with high to excellent yields of products.
引用
收藏
页码:2699 / 2704
页数:6
相关论文
共 50 条
  • [31] NABH4 REDUCTION OF KETONES IN THE SOLID-STATE
    TODA, F
    KIYOSHIGE, K
    YAGI, M
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1989, 28 (03) : 320 - 321
  • [32] A standard protocol for NaBH4 reduction of CDOM and HS
    Schendorf, Tara Marie
    Del Vecchio, Rossana
    Koech, Kevin
    Blough, Neil V.
    LIMNOLOGY AND OCEANOGRAPHY-METHODS, 2016, 14 (06): : 414 - 423
  • [33] Reduction of amides with NaBH4 in diglyme at 162°C
    Zhu, HJ
    Lu, KT
    Sun, GR
    He, JB
    Li, HQ
    Pittman, CU
    NEW JOURNAL OF CHEMISTRY, 2003, 27 (02) : 409 - 413
  • [34] Synthesis and characterization of NiFe2O4@Cu nanoparticles as a magnetically recoverable catalyst for reduction of nitroarenes to arylamines with NaBH4
    Zeynizadeh, Behzad
    Mohammadzadeh, Iman
    Shokri, Zahra
    Hosseini, Seyed Ali
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2017, 500 : 285 - 293
  • [35] A mild, convenient, non-acidic conversion of enol ethers into alcohols using Hg(OAc)(2)-NaBH4
    Crouch, RD
    Mitten, JV
    Span, AR
    Dai, HG
    TETRAHEDRON LETTERS, 1997, 38 (05) : 791 - 794
  • [36] REDUCTION OF CYCLIC ANHYDRIDES WITH NABH4 - VERSATILE LACTONE SYNTHESIS
    BAILEY, DM
    JOHNSON, RE
    JOURNAL OF ORGANIC CHEMISTRY, 1970, 35 (10): : 3574 - &
  • [37] Synthesis of -Benzylthiobenzimidazoleacetonitriles and Their Chemoselective Reduction of the Double Bond with NaBH4
    Sadhu, Srinivas Rao
    Reddy, Chittireddy Venkata Ramana
    Dubey, Pramod Kumar
    JOURNAL OF HETEROCYCLIC CHEMISTRY, 2016, 53 (01) : 74 - 79
  • [38] Understanding the Kinetics and Reduction of Methylene Blue Using NaBH4
    Patel, P.
    Maliekal, P. J.
    Lingayat, S.
    Badani, P. M.
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY B, 2022, 16 (05) : 869 - 876
  • [39] Asymmetric Induction by a-Cyclodextrins in NaBH4 Reduction of Ketones
    Kwanghee, Koh Park
    Sim, W.-J.
    Joon Woo Park
    1997, (27):
  • [40] Chemoselective reduction of aldehydes via a combination of NaBH4 and acetylacetone
    Sui, Guoqing
    Lv, Qingyun
    Song, Xiaoqing
    Guo, Huihui
    Dai, Jiatong
    Ren, Li
    Lee, Chi-Sing
    Zhou, Wenming
    Hao, Hong-Dong
    NEW JOURNAL OF CHEMISTRY, 2019, 43 (39) : 15793 - 15796