The direct decarboxylative allylation of N-arylglycine derivatives by photoredox catalysis

被引：39

作者：

Duan, Yingqian ^{[1
]}

Zhang, Muliang ^{[1
]}

Ruzi, Rehanguli ^{[1
]}

Wu, Zhongkai ^{[1
]}

Zhu, Chengjian ^{[1
,2
]}

机构：

[1] Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China

[2] Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

来源：

ORGANIC CHEMISTRY FRONTIERS | 2017年 / 4卷 / 04期

关键词：

ALPHA-AMINO-ACIDS; INDUCED RADICAL ALLYLATION; CARBOXYLIC-ACIDS; BOND FORMATION; TRIFLUOROMETHYLATION; FUNCTIONALIZATION; DIFUNCTIONALIZATION; SULFONES; ALKENES;

D O I：

10.1039/c6qo00711b

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The direct decarboxylative allylation of N-arylglycine derivatives has been accomplished via visible-light photoredox catalysis. With the substrates of N-aryl glycine derivatives and allylsulfone, a series of allylation products by a redox-neutral process were readily synthesized in good yields under mild conditions. The further utility of this allylation reaction has also been evaluated for valuable structural motifs.

引用

页码：525 / 528

页数：4

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