The direct decarboxylative allylation of N-arylglycine derivatives by photoredox catalysis

被引：39
|
作者：
Duan, Yingqian [1 ]
Zhang, Muliang [1 ]
Ruzi, Rehanguli [1 ]
Wu, Zhongkai [1 ]
Zhu, Chengjian [1 ,2 ]
机构：
[1] Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China
[2] Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
来源：
ORGANIC CHEMISTRY FRONTIERS | 2017年 / 4卷 / 04期
关键词：
ALPHA-AMINO-ACIDS; INDUCED RADICAL ALLYLATION; CARBOXYLIC-ACIDS; BOND FORMATION; TRIFLUOROMETHYLATION; FUNCTIONALIZATION; DIFUNCTIONALIZATION; SULFONES; ALKENES;
D O I：
10.1039/c6qo00711b
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The direct decarboxylative allylation of N-arylglycine derivatives has been accomplished via visible-light photoredox catalysis. With the substrates of N-aryl glycine derivatives and allylsulfone, a series of allylation products by a redox-neutral process were readily synthesized in good yields under mild conditions. The further utility of this allylation reaction has also been evaluated for valuable structural motifs.
引用
收藏
页码：525 / 528
页数：4
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