Total synthesis of (+)-virgatusin via AlCl3-catalyzed [3+2] cycloaddition

被引：66
|
作者：
Sanders, Shanina D. [1 ]
Ruiz-Olalla, Andrea [1 ]
Johnson, Jeffrey S. [1 ]
机构：
[1] Univ N Carolina, Dept Chem, Chapel Hill, NC 27500 USA
来源：
CHEMICAL COMMUNICATIONS | 2009年 / 34期
关键词：
SUBSTITUTED TETRAHYDROFURAN LIGNAN; DONOR-ACCEPTOR CYCLOPROPANES; DIASTEREOSELECTIVE SYNTHESIS; ENANTIOSELECTIVE SYNTHESIS; STEREOSELECTIVE-SYNTHESIS; (-)-VIRGATUSIN; ALDEHYDES; ACID; VIRGATUSIN;
D O I：
10.1039/b911765b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The AlCl3-catalyzed cycloaddition of a donor-acceptor (don-acc) cyclopropane and piperonal succinctly provides the core of virgatusin in a selective, high-yielding manner.
引用
收藏
页码：5135 / 5137
页数：3
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