Kinetics of oxidation of fullerene C60 with dimethyldioxirane

被引：2
|
作者：
Antipin, AV [1 ]
Shishlov, NM [1 ]
Grabovskii, SA [1 ]
Kabal'nova, NN [1 ]
机构：
[1] Russian Acad Sci, Ufa Res Ctr, Inst Organ Chem, Ufa 450054, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2004年 / 53卷 / 04期
关键词：
dimethyldioxirane; fullerene; kinetics; oxidation; free radicals;
D O I：
10.1023/B:RUCB.0000037845.82051.50
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The kinetics of the reaction of dimethyldioxirane with fullerene C-60 was studied, and the activation parameters logk = (8.3+/-0.8) - (14.2+/-0.9)/theta, (theta = 2.3RT kcal mol(-1)) (20-45 degreesC) were determined. The formation of paramagnetic particles was detected.
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页码：800 / 802
页数：3
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