Kinetics of oxidation of fullerene C60 with dimethyldioxirane

被引:2
|
作者
Antipin, AV [1 ]
Shishlov, NM [1 ]
Grabovskii, SA [1 ]
Kabal'nova, NN [1 ]
机构
[1] Russian Acad Sci, Ufa Res Ctr, Inst Organ Chem, Ufa 450054, Russia
关键词
dimethyldioxirane; fullerene; kinetics; oxidation; free radicals;
D O I
10.1023/B:RUCB.0000037845.82051.50
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The kinetics of the reaction of dimethyldioxirane with fullerene C-60 was studied, and the activation parameters logk = (8.3+/-0.8) - (14.2+/-0.9)/theta, (theta = 2.3RT kcal mol(-1)) (20-45 degreesC) were determined. The formation of paramagnetic particles was detected.
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页码:800 / 802
页数:3
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