Performance improvement of poly(acrylonitrile-vinyl acetate) by activation of poly(methyl methacrylate)

被引：54
|
作者：
Rao, M. M. [1 ]
Liu, J. S. [2 ]
Li, W. S. [1 ,2 ,3 ]
Liang, Y. [1 ]
Liao, Y. H. [1 ]
Zhao, L. Z. [1 ]
机构：
[1] S China Normal Univ, Sch Chem & Environm, Guangzhou 510006, Guangdong, Peoples R China
[2] S China Univ Technol, Coll Mat Sci & Engn, Guangzhou 510641, Peoples R China
[3] Guangdong Univ, Key Lab Electrochem Technol Energy Storage & Powe, Guangzhou 510006, Guangdong, Peoples R China
来源：
JOURNAL OF POWER SOURCES | 2009年 / 189卷 / 01期
关键词：
Lithium ion battery; Gel polymer electrolyte; P(AN-VAc); P(AN-VAc)/PMMA; LITHIUM-ION BATTERIES; BLEND POLYMER ELECTROLYTES; PHASE INVERSION TECHNIQUE; GEL ELECTROLYTES; METHYL METHACRYLATE; PVC/PMMA BLEND; POLYACRYLONITRILE; CONDUCTIVITY; PMMA; PAN;
D O I：
10.1016/j.jpowsour.2008.08.049
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Poly(acrylonitrile-vinyl acetate) (P(AN-VAc)) was synthesized by emulsion polymerization with different mole ratios of acrylonitrile (AN) to vinyl acetate (VAc). P(AN-VAc) membrane was prepared with phase inversion method and was activated by poly(methyl methacrylate) (PMMA) to prepare a new type of gel polymer electrolyte matrix, P(AN-VAc)/PMMA. The performances of the synthesized copolymer and prepared polymer matrixes were characterized with FTIR, TGA, SEM, electrochemical and mechanical test. Compared with P(AN-VAc), P(AN-VAc)/PMMA is better as the matrix for gel polymer electrolyte for lithium ion battery use. P(AN-VAc)/PMMA has higher mechanical strength than P(AN-VAc) and the gel polymer electrolyte based on P(AN-VAc)/PMMA has higher electrochemical and chemical stability and ionic conductivity. (C) 2008 Elsevier B.V. All rights reserved.
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页码：711 / 715
页数：5
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