Synthesis and characterization of [(η6-arene)Ru(R3P)Cl2] complexes

被引：0
|
作者：
Redwine, KD [1 ]
Hansen, HD [1 ]
Bowley, S [1 ]
Isbell, J [1 ]
Sanchez, M [1 ]
Vodak, D [1 ]
Nelson, JH [1 ]
机构：
[1] Univ Nevada, Dept Chem, Reno, NV 89557 USA
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 2000年 / 30卷 / 03期
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D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis and characterization of the complexes: [(eta(6)-arene)Ru(R3P)Cl-2] [(arene = C6Ho, MeC6H5, p-MeC6H4CHMe2, and C6Me6; R3P = Ph2PCH=CH2 (DPVP); PhP(CH=CH2)(2) (DVPP); Ph2PCH2CH=CH2 (ADPP); and 1-phenyl-3,4-dimethylphosphole (DMPP)] are described. These complexes have been characterized by elemental analyses, physical properties, H-1, C-13: 1H), and P-31(H-1) NMR spectroscopy, infrared spectroscopy, cyclic voltammetry and in most cases by X-ray crystallography.
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页码：379 / 407
页数：29
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