Fabrication of cuprous nanoparticles in MIL-101: an efficient adsorbent for the separation of olefin-paraffin mixtures

被引：80

作者：

Chang, Ganggang ^{[1
]}

Bao, Zongbi ^{[1
]}

Ren, Qilong ^{[1
]}

Deng, Shuguang ^{[1
,2
]}

Zhang, Zhiguo ^{[1
]}

Su, Baogen ^{[1
]}

Xing, Huabin ^{[1
]}

Yang, Yiwen ^{[1
]}

机构：

[1] Zhejiang Univ, Dept Chem & Biol Engn, Key Lab Biomass Chem Engn, Minist Educ, Hangzhou 310027, Zhejiang, Peoples R China

[2] New Mexico State Univ, Dept Chem Engn, Las Cruces, NM 88003 USA

来源：

RSC ADVANCES | 2014年 / 4卷 / 39期

基金：

中国国家自然科学基金;

关键词：

METAL-ORGANIC FRAMEWORK; CARBON MOLECULAR-SIEVE; ADSORPTIVE SEPARATION; BINARY-MIXTURES; SURFACE-AREA; PROPANE; PROPYLENE; ETHANE; ETHYLENE; EQUILIBRIA;

D O I：

10.1039/c4ra02125h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Various amounts of Cu+ nanoparticles were successfully deposited to the pores of metal-organic frameworks MIL-101 with a doublesolvent method. An optimized, cuprous-loadedMIL-101 was shown to have an enhanced ethylene adsorption capacity and higher ethyleneethane selectivity (14.0), compared to pure MIL-101 (1.6). The great improvement in selectivity can be attributed to the newly generated nano-sized cuprous chloride particles that can selectively interact with the carbon-carbon double bond in ethylene through pi-complexation.

引用

页码：20230 / 20233

页数：4

共 50 条

[41] Fabrication of a novel positively charged MIL-101(Al and Cr)-NH2/polyvinyl alcohol nanofiltration membrane for methylene blue cationic dye separation
Ghazi, Mohsen Mehdipour
Bagherian, Abbas
DESALINATION AND WATER TREATMENT, 2022, 267 : 293 - 303
[42] Bimetallic Au-Pd alloy nanoparticles supported on MIL-101(Cr) as highly efficient catalysts for selective hydrogenation of 1,3-butadiene
Liu, Lili
Zhou, Xiaojing
Guo, Luxia
Yan, Shijuan
Li, Yingjie
Jiang, Shuai
Tai, Xishi
RSC ADVANCES, 2020, 10 (55) : 33417 - 33427
[43] Synthesis and characterization of MIL-101(Cr) intercalated by polyaniline composite, doped with silica nanoparticles and its evaluation as an efficient solid-phase extraction sorbent
Ghiasvand, Ali Reza
Ghaedrahmati, Leila
Heidari, Nahid
Haddad, Paul R.
Farhadi, Saeid
JOURNAL OF SEPARATION SCIENCE, 2018, 41 (20) : 3910 - 3917
[44] Dye-sensitized MIL-101 metal organic frameworks loaded with Ni/NiOx nanoparticles for efficient visible-light-driven hydrogen generation
Liu, Xin-Ling
Wang, Rong
Zhang, Ming-Yi
Yuan, Yu-Peng
Xue, Can
APL MATERIALS, 2015, 3 (10):
[45] Silver nanoparticles stabilized by a metal-organic framework (MIL-101(Cr)) as an efficient catalyst for imine production from the dehydrogenative coupling of alcohols and amines
Gumus, Ilkay
Karatas, Yasar
Gulcan, Mehmet
CATALYSIS SCIENCE & TECHNOLOGY, 2020, 10 (15) : 4990 - 4999
[46] Optimized fabrication of mixed matrix membranes based on amino-MIL-101(Cr) for highly efficient CO2 separation
Yang K.
Ruan X.
Dai Y.
Wang J.
He G.
Huagong Xuebao/CIESC Journal, 2020, 71 (01): : 329 - 336
[47] Bimetallic Au-Ni alloy nanoparticles in a metal-organic framework (MIL-101) as efficient heterogeneous catalysts for selective oxidation of benzyl alcohol into benzaldehyde
Liu, Lili
Tai, Xishi
Zhou, Xiaojing
Hou, Jianxin
Zhang, Zihua
JOURNAL OF ALLOYS AND COMPOUNDS, 2019, 790 : 326 - 336
[48] Ni-Pt nanoparticles supported on MIL-101 as highly efficient catalysts for hydrogen generation from aqueous alkaline solution of hydrazine for chemical hydrogen storage
Cao, Nan
Su, Jun
Luo, Wei
Cheng, Gongzhen
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2014, 39 (18) : 9726 - 9734
[49] Separation of n-butanol from aqueous mixtures using TiO2 and h-BN functionalized MIL-101(Cr) incorporated PVDF mixed matrix membranes
Kachhadiya, Dipeshkumar D.
Murthy, Z. V. P.
SEPARATION AND PURIFICATION TECHNOLOGY, 2023, 306
[50] Poly (ether-block amide) thin-film membranes containing functionalized MIL-101 MOFs for efficient separation of CO2/CH4
Salestan, Saeed Khoshhal
Pirzadeh, Kasra
Rahimpour, Ahmad
Abedini, Reza
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, 2021, 9 (05):

← 1 2 3 4 5 →