Terpyridine complexes of first row transition metals and electrochemical reduction of CO2 to CO

被引：158

作者：

Elgrishi, Noemie ^{[1
]}

Chambers, Matthew B. ^{[1
]}

Artero, Vincent ^{[2
]}

Fontecave, Marc ^{[1
]}

机构：

[1] Univ Paris 06, UMR 8229, CNRS, Lab Chim Proc Biol,Coll France, F-75231 Paris 05, France

[2] Univ Grenoble Alpes, CNRS UMR 5249, CEA, Lab Chim & Biol Met, F-38054 Grenoble 9, France

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2014年 / 16卷 / 27期

关键词：

CARBON-DIOXIDE; ELECTROCATALYTIC REDUCTION; VISIBLE-LIGHT; ELECTROPOLYMERIZED FILMS; HOMOGENEOUS CATALYSIS; MOLECULAR CATALYSIS; WATER; HYDROGEN; OXIDATION; 2,2-BIPYRIDINE;

D O I：

10.1039/c4cp00451e

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Homoleptic terpyridine complexes of first row transition metals are evaluated as catalysts for the electrocatalytic reduction of CO2. Ni and Co-based catalytic systems are shown to reduce CO2 to CO under the conditions tested. The Ni complex was found to exhibit selectivity for CO2 over proton reduction while the Co-based system generates mixtures of CO and H-2 with CO:H-2 ratios being tuneable through variation of the applied potential.

引用

页码：13635 / 13644

页数：10

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