Characterization of nanostructured binary molybdenum oxide catalyst precursors for propene oxidation

被引:5
|
作者
Wagner, J. B.
Othman, N. D.
Su, D. S.
Hamid, S. B. A.
Schloegl, R.
机构
[1] Max Planck Gesell, Dept Inorgan Chem, Fritz Harber Inst, D-14195 Berlin, Germany
[2] Univ Malaya, COMBICAT, Kuala Lumpur 50603, Malaysia
来源
关键词
HRTEM; molybdenum oxide; selective oxidation;
D O I
10.1111/j.1365-2818.2006.01623.x
中图分类号
TH742 [显微镜];
学科分类号
摘要
High-resolution transmission electron microscopy characterization of molybdenum oxide catalyst precursors is carried out for a better understanding of the mechanisms leading to the active catalytic material. The precipitated material consists of both large-unit cell crystals and randomly orientated clusters on a 3-5 nm scale. The crystalline clusters are embedded in non-crystalline material, preventing the formation of large well-defined inactive orthorhombic MoO3 crystals during activation of the catalyst material.
引用
收藏
页码:216 / 219
页数:4
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