Titanium dioxide as a mild and efficient catalyst for conversion of epoxides to thiiranes

被引:16
|
作者
Yadollahi, B
Tangestaninejad, S
Habibi, MH
机构
[1] Inst Adv Studies Basic Sci, Dept Chem, Gava Zang, Zanjan, Iran
[2] Esfahan Univ, Dept Chem, Esfahan, Iran
关键词
titanium dioxide; catalysis; epoxide; thiirane; ammonium thiocyanate;
D O I
10.1081/SCC-200026239
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Titanium dioxide (TiO2) efficiently catalyze the reaction of a variety of epoxides with ammonium thiocyanate in refluxing acetonitrile to afford the corresponding thiirane in high to excellent yields.
引用
收藏
页码:2823 / 2827
页数:5
相关论文
共 50 条
  • [21] Mild, efficient, and convenient conversion of oxiranes to thiiranes with ammonium thiocyanate and thiourea in the presence of cerium(IV) polyoxometallate
    Mirkhani, V
    Tangestaninejad, S
    Alipanah, L
    SYNTHETIC COMMUNICATIONS, 2002, 32 (04) : 621 - 626
  • [22] AN EFFICIENT CONVERSION OF EPOXIDES TO THIIRANES WITH THIOUREA CATALYZED BY NANO CRYSTALLINE SNO2/AL2O3
    PhaniRaja, K.
    Pachipulusula, Shravya
    Malleswarareddy, P.
    HETEROCYCLIC LETTERS, 2021, 11 (04): : 569 - 577
  • [23] A mild and efficient synthesis of β-amino alcohols from epoxides using a mesoporous aluminosilicate catalyst
    Robinson, Mathew W. C.
    Timms, David A.
    Williams, Sarah M.
    Graham, Andrew E.
    TETRAHEDRON LETTERS, 2007, 48 (36) : 6249 - 6251
  • [24] Copolymerization of lactide, epoxides and carbon dioxide: a highly efficient heterogeneous ternary catalyst system
    Li, Xiang
    Duan, Ran-long
    Hu, Chen-yang
    Pang, Xuan
    Deng, Ming-xiao
    POLYMER CHEMISTRY, 2021, 12 (11) : 1700 - 1706
  • [26] Mild and efficient deoxygenation of epoxides with bis(cyclopentadienyl)titanium(IV) dichloride-indium system
    Choi, KH
    Choi, KI
    Kirn, JH
    Yoon, CM
    Yoo, BW
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2005, 26 (10) : 1495 - 1496
  • [27] A new and efficient conversion of olefins into thiiranes using diethoxyoxophosphoranesulfenyl chloride
    Kowara, J
    Skowronska, A
    Michalski, J
    Capozzi, G
    HETEROATOM CHEMISTRY, 1997, 8 (05) : 429 - 433
  • [28] Solvent-free conversion of epoxides to thiiranes by thiourea/NH4Cl system
    Zeynizadeh, Behzad
    Yeghaneh, Samal
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2008, 183 (09) : 2280 - 2286
  • [29] Hydrogensulphate ionic liquids as an efficient catalyst for the synthesis of cyclic carbonates from carbon dioxide and epoxides
    Jasiak, Katarzyna
    Siewniak, Agnieszka
    Kopczyliska, Katarzyna
    Chrobok, Anna
    Baj, Stefan
    JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY, 2016, 91 (11) : 2827 - 2833
  • [30] On the conversion of titanium dioxide.
    Schossberger, T
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1942, 104 (4/5): : 358 - 374