The Simulation of an Industrial Fixed Bed Reactor for Methanol Dehydration to Dimethyl Ether

被引:2
|
作者
Zhang, L. [1 ]
Zhang, H. T. [1 ]
Ying, W. Y. [1 ]
Fang, D. Y. [1 ]
机构
[1] E China Univ Sci & Technol, Sch Chem Engn, POB 374,130 Meilong Rd, Shanghai 200237, Peoples R China
关键词
dimethyl ether; internal effectiveness factor; methanol; reactor; simulation; CONVERSION;
D O I
10.1080/15567036.2012.750404
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Compared to methane and methanol, dimethyl ether seems to be a superior candidate for high quality diesel fuel in the near future. To meet the continuously increasing global requirements, a larger scale reactor is needed to produce more dimethyl ether. A heterogeneous one-dimensional model was developed to simulate a staged adiabatic fixed bed reactor for the catalytic dehydration of methanol to dimethyl ether. To verify the proposed model, the simulated catalyst bed temperature has been compared to available data from an industrial reactor. A good agreement has been found between the simulation and plant data. Also, the effects of some operational parameters, such as feed flow rates, the inlet temperatures of methanol, pressure, and catalyst particle diameter on reactor behavior were investigated. The simulated results show that this model is reasonable and reliable.
引用
收藏
页码:2166 / 2174
页数:9
相关论文
共 50 条
  • [41] The Synthesis and Catalytic Activity of Slurry Catalyst for Methanol Dehydration to Dimethyl Ether
    Liu, L.
    Huang, W.
    Huang, J.
    Gao, Z. -H.
    Yin, L. -H.
    ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS, 2012, 34 (5-8) : 682 - 691
  • [42] Dehydration of methanol over Nordstrandite based catalysts for dimethyl ether synthesis
    Seo, Chang Won
    Jung, Kwang Deok
    Lee, Kwan Young
    Yoo, Kye Sang
    JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2009, 15 (05) : 649 - 652
  • [43] Dimethyl ether synthesis via methanol dehydration: Effect of zeolite structure
    Catizzone, Enrico
    Aloise, Alfredo
    Migliori, Massimo
    Giordano, Girolamo
    APPLIED CATALYSIS A-GENERAL, 2015, 502 : 215 - 220
  • [44] Supported WOx-based catalysts for methanol dehydration to dimethyl ether
    Ladera, R.
    Finocchio, E.
    Rojas, S.
    Busca, G.
    Fierro, J. L. G.
    Ojeda, M.
    FUEL, 2013, 113 : 1 - 9
  • [45] Catalytic Dehydration of Methanol to Dimethyl Ether Catalyzed by Aluminum Phosphate Catalysts
    Yaripour, F.
    Mollavali, A.
    Jam, Sh. Mohammadi
    Atashi, H.
    ENERGY & FUELS, 2009, 23 (3-4) : 1896 - 1900
  • [46] Modeling and optimization of methanol oxidation over metal oxide catalyst in an industrial fixed bed reactor
    Ghahraloud, H.
    Farsi, M.
    JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS, 2017, 81 : 95 - 103
  • [47] Mass Spectrometry and Quantum Chemistry Study on the Methanol Dehydration to Dimethyl Ether
    Liang, Yu
    Mao, Yan-Mei
    Zhong, Kai
    Liang, Ze-Bin
    Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities, 2001, 22 (03): : 465 - 469
  • [48] Selective dehydration of methanol to dimethyl ether on ZSM-5 nanocrystals
    Rownaghi, Ali A.
    Rezaei, Fateme
    Stante, Matteo
    Hedlund, Jonas
    APPLIED CATALYSIS B-ENVIRONMENTAL, 2012, 119 : 56 - 61
  • [49] Mass spectrometry and quantum chemistry study on the methanol dehydration to dimethyl ether
    Liang, Y
    Mao, YM
    Zhong, K
    Liang, ZB
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2001, 22 (03): : 465 - 469
  • [50] Hierarchical mesoporous ZSM-5 for the dehydration of methanol to dimethyl ether
    Yang, Qi
    Zhang, Haitao
    Kong, Meng
    Bao, Xiuxiu
    Fei, Jinhua
    Zheng, Xiaoming
    CHINESE JOURNAL OF CATALYSIS, 2013, 34 (08) : 1576 - 1582