3-CYANO-4,6-DIMETHYL-5-R-PYRIDINE-2-SULFONYL CHLORIDES AND N-SUBSTITUTED SULFONYLAMIDES BASED ON THEM

被引：4

作者：

Dmitrieva, I. G. ^{[1
]}

Dyadyuchenko, L. V. ^{[1
]}

Strelkov, V. D. ^{[2
]}

Kaigorodova, E. A. ^{[3
]}

机构：

[1] Kuban State Agrarian Univ, Krasnodar 350044, Russia

[2] All Russia Res Inst Biol Plants Protect, Krasnodar 350039, Russia

[3] Kuban State Univ Technol, Krasnodar 350072, Russia

来源：

CHEMISTRY OF HETEROCYCLIC COMPOUNDS | 2009年 / 45卷 / 09期

关键词：

sulfonylamides; sulfonyl chlorides; oxidative chlorination; synthesis; elimination;

D O I：

10.1007/s10593-009-0386-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

3-Cyanopyridine-2-sulfonyl chlorides were synthesized by the oxidative chlorination of the respective 3-cyanopyridine-2(1H)-2-thiones. It was established that 3-cyano-4,6-dimethylpyridine-2-sulfonyl chloride eliminates a SO(2) molecule at the isolation stage. N-Substituted sulfonylamides based on the latter were obtained by the reaction of the crude sulfonyl chloride with amines in an aqueous medium.

引用

页码：1047 / 1052

页数：6

共 43 条

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