High capacity immobilization of TRPO waste by Gd2Zr2O7 pyrochlore

被引：29
|
作者：
Lu, Xirui [1 ,2 ]
Ding, Yi [2 ]
Dan, Hui [2 ]
Wen, Mingfen [3 ]
Mao, Xueli [2 ]
Wu, Yanlin [4 ]
Wang, Xiaolin [1 ]
机构：
[1] China Acad Engn Phys, Mianyang 621900, Peoples R China
[2] Southwest Univ Sci & Technol, Key Subject Lab Natl Def Radioact Waste & Environ, Mianyang 621010, Peoples R China
[3] Tsinghua Univ, Inst Nucl & New Energy Technol, Beijing 100084, Peoples R China
[4] Grad Univ Adv Studies, Hayama 2400193, Japan
来源：
MATERIALS LETTERS | 2014年 / 136卷
基金：
中国国家自然科学基金;
关键词：
Pyrochlore; TRPO wastes; Solubility; Nuclear waste forms; Chemical durability; ACTINIDES; MATRIX;
D O I：
10.1016/j.matlet.2014.08.021
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
This paper describes the immobilization of trialkyl phosphine oxides (TRPO) waste in Gd2Zr2O7 pyrochlore through designed elements occupation. It was found that up to 45 wt% TRPO waste could be successfully incorporated in the Gd2Zr2O7 pyrochlore structure and the ordered pyrochlore structure was maintained. The Gd and Zr position could be replaced by the elements of TRPO wastes in the same time through designed elements occupation. Furthermore, the results of anti-leaching experiment shown that the immobilized TRPO waste have good chemical durability. This route provides an alternative flexible system to tackle radioactive wastes arising from the advanced nuclear reactors. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码：1 / 3
页数：3
相关论文
共 50 条
  • [31] A DFT plus U study of Pu immobilization in Gd2Zr2O7
    Zhao, F. A.
    Xiao, H. Y.
    Jiang, M.
    Liu, Z. J.
    Zu, X. T.
    [J]. JOURNAL OF NUCLEAR MATERIALS, 2015, 467 : 937 - 948
  • [32] Ultra-fast immobilization of simulated TRPO waste into as-prepared Gd 2 Zr 2 O 7 by flash sintering
    Zuo, Shibing
    Shu, Xiaoyan
    Fu, Yulu
    He, Yang
    Zhao, Guoliang
    Wei, Guilin
    Wen, Mingfen
    Luo, Fen
    Ding, Congcong
    Xu, Chen
    Lu, Xirui
    [J]. CERAMICS INTERNATIONAL, 2024, 50 (16) : 28867 - 28876
  • [33] The structure and thermal properties of Nd and Ce-doped Gd2Zr2O7 pyrochlore for nuclear waste forms
    Chen, Shunzhang
    Huang, Di
    Fan, Long
    Lu, Xirui
    Ma, Dengsheng
    Ren, Wei
    Bian, Liang
    [J]. ADVANCES IN ENERGY, ENVIRONMENT AND MATERIALS SCIENCE, 2017, : 275 - 278
  • [34] Heat capacity of the frustrated magnetic pyrochlores Gd2Zr2O7 and Gd2Hf2O7
    Durand, Alice M.
    Klavins, Peter
    Corruccini, L. R.
    [J]. JOURNAL OF PHYSICS-CONDENSED MATTER, 2008, 20 (23)
  • [35] Gd2Zr2O7 pyrochlore Potential host matrix for some constituents of thoria based reactor's waste
    Mandal, B. P.
    Pandey, M.
    Tyagi, A. K.
    [J]. JOURNAL OF NUCLEAR MATERIALS, 2010, 406 (02) : 238 - 243
  • [36] Evaluation of oxidation and thermal cyclic behavior of YSZ, Gd2Zr2O7 and YSZ/Gd2Zr2O7 TBCs
    Doleker, Kadir Mert
    Ozgurluk, Yasin
    Ahlatci, Hayrettin
    Karaoglanli, Abdullah Cahit
    [J]. SURFACE & COATINGS TECHNOLOGY, 2019, 371 : 262 - 275
  • [37] Shock Synthesis of Gd2Zr2O7
    Sekine, Toshimori
    Zhou, Qiang
    Chen, Pengwan
    Tan, Zhen
    Ran, Haotian
    Liu, Jianjun
    [J]. EXPLOSION SHOCK WAVES AND HIGH STRAIN RATE PHENOMENA, 2019, 13 : 31 - 34
  • [38] Oxidation Behavior of Single-Layer Gd2Zr2O7, and Gd2Zr2O7/YbSZ, and Double-Layer YSZ + Gd2Zr2O7/YbSZ Thermal Barrier Coatings
    Tabeshfar, Mohadese
    Dini, Ghasem
    Salehi, Mehdi
    Wiik, Kjell
    [J]. HIGH TEMPERATURE CORROSION OF MATERIALS, 2023, 99 (1-2) : 133 - 149
  • [39] Structural, dielectric and electrical properties of pyrochlore-type Gd2Zr2O7 ceramic
    Saurabh K. Sharma
    Hari S. Mohanty
    Dillip K. Pradhan
    Ajay Kumar
    Vivek K. Shukla
    Fouran Singh
    Pawan K. Kulriya
    [J]. Journal of Materials Science: Materials in Electronics, 2020, 31 : 21959 - 21970
  • [40] A DFT plus U study on the thermodynamic properties of defective Gd2Zr2O7 pyrochlore
    Li, Menglu
    Li, Pengcheng
    Xiao, Haiyan
    Zhang, Haibin
    Zu, Xiaotao
    [J]. JOURNAL OF NUCLEAR MATERIALS, 2020, 542
12345