Carbonyl-metal fragment insertion into eight-vertex [closo-1-CB7H8]-.: Facile synthesis of ten-vertex metalladicarbollide complexes [2,2,2-(CO)3-1-OH-closo-2,1,10-MC2B7H8]n- {M = Fe, Ru (n=0), Mn, Re (n=1)}

被引：15

作者：

Franken, Andreas ^{[1
]}

Lei, Peng ^{[1
]}

McGrath, Thomas D. ^{[1
]}

Stone, F. Gordon A. ^{[1
]}

机构：

[1] Baylor Univ, Dept Chem & Biochem, Waco, TX 76798 USA

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 32期

关键词：

D O I：

10.1039/b607768d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Insertion of {M(CO)(4)} fragments (M = Fe, Ru, Mn, Re) into the eight-vertex monocarborane anion [closo-1-CB7H8](-) affords ten-vertex metal - dicarbollide complexes.

引用

页码：3423 / 3425

页数：3

共 47 条

[31] New triosmium-iridium clusters:: Synthesis and molecular structure of [Os3Ir2(Cp*)2(μ-OH)(μ-CO)2(CO)8Cl] (1), [Os3IrCp*(μ-OH)(CO)10Cl] (2), [Os3IrCp*(μ-H)(μ-Cl) (η3,μ3-C5H2N(NH2)Br)(CO)9] (3) and [Os3IrCp*(μ-Cl)2 (η2,μ3-C5H3N(NH)Br)(CO)7] (4)
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JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2008, 693 (8-9) : 1528 - 1535
[32] THE HETERONUCLEAR CLUSTER CHEMISTRY OF THE GROUP 1B METALS .6. SYNTHESIS, STRUCTURES, AND DYNAMIC BEHAVIOR OF THE BIMETALLIC HEXANUCLEAR GROUP-1B METAL CLUSTER COMPOUNDS [M2RU4(MU-3-H)2(MU-PH2P(CH2)NPPH2)(CO)12] (M=CU OR AG,N=1-6) - X-RAY CRYSTAL-STRUCTURES OF [CU2RU4(MU-3-H)2-(MU-PH2P(CH2)NPPH2)(CO)12](N = 2, 3, OR 5)
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[33] CHEMISTRY OF C-TRIMETHYLSILYL-SUBSTITUTED HETEROCARBORANES .15. SYNTHETIC, SPECTROSCOPIC, REACTIVITY, AND BONDING STUDIES ON THE CARBONS APART CLOSO-1-SN-2-(SIME3)-4-(R)-2,4-C2B4H4 - CRYSTAL-STRUCTURES OF THE DONOR-ACCEPTOR COMPLEXES 1-SN(L)-2,4-(SIME3)2-2,4-C2B4H4 [R=SIME3, ME, L=2,2'-C10H8N2, 2,2'-C8H6N4, OR (ETA(5)-C5H5)FE(ETA(5)-C5H4CH2(ME)2N)]
HOSMANE, NS
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MAGUIRE, JA
ORGANOMETALLICS, 1994, 13 (04) : 1411 - 1423
[34] Mechanism of interconversion of the silica-supported tin alkyl complexes (=SiO)3-nSn(n-C4H9)n+1,n=0,1,2.: Synthesis and characterization of the tin-containing polyhedral oligo-silsesquioxanes [(c-C5H9)7Si8O12(CH3)2Sn(n-C4H9)3], [(c-C5H9)7Si7O11 (OH)Sn(n-C4H9)2] and [(c-C5H9)7Si7O12Sn(n-C4H9)] as possible models for the expected surface structures
Nédez, C
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COMPTES RENDUS CHIMIE, 2004, 7 (8-9) : 785 - 796
[35] Synthesis and characterization of transition metal stabilized carbocations of the types [CP*(CO)2Fe{μ-(CnH2n-1}M(CO)xCp]PF6 (x=2, M = Fe or Ru; x=3, M = W, Cp* = η5-C5(CH3)5; Cp = η5-C5H5; n=3-6) and [Cp(CO)2Ru{μ-(CnH2n-1)}W(CO)3Cp]PF6 (n=3-5) and the crystal structures of the complexes [Cp*(CO)2Fe(CH2)3Ru(CO)2Co], [Cp*(CO)2Fe(CH2)5Ru(CO)2Cp], [Cp*(CO)2Fe-(CH2)5W(CO)3Cp], and [Cp(CO)2Ru(CH2)5W(CO)3Cp]
Changamu, Evans O.
Friedrich, Holger B.
Rademeyer, Melanie
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2007, 692 (12) : 2456 - 2472
[36] Synthesis and Characterization of New Thebaine Derivatives as Potential Opioid Agonists and Antagonists: 2-[N-(1H-Tetrazol-5-yl)-6,14-endo-etheno-6,7,8,14-tetrahydrothebaine-7α-yl]-5-phenyl-1,3,4-oxadiazoles
Yildirir, Yilmaz
Pamir, Ozgur
Yavuz, Serkan
Disli, Ali
JOURNAL OF HETEROCYCLIC CHEMISTRY, 2013, 50 : E93 - E99
[37] Synthesis, characterization, and crystal structures of a series of osmium-rhodium mixed-metal carbonyl clusters:: [N(PPh3)2][Os6Rh(μ-H)2(CO)20], [Os6Rh(μ-H)7(μ-CO)(CO)18], [Os6Rh(μ-H)9(CO)18], and [Os3Rh(μ-CO)(CO)9(μ4-η2-PhC2Ph)(μ2-η1:η2-PhC2PhH)]
Wong, WT
ORGANOMETALLICS, 1999, 18 (17) : 3474 - 3481
[38] Linked and fused tungstaborane clusters:: Synthesis, characterization, and electronic structures of bis-{(η5-C5Me5W)2B5H8}2 and (η5-C5Me5W)2P{Fe(CO)3}nB6-nH10-n, n=0,1
Bose, Shubhankar Kumar
Ghosh, Sundargopal
Noll, Bruce C.
Halet, Jean-Francois
Saillard, Jean-Yves
Vega, Anders
ORGANOMETALLICS, 2007, 26 (22) : 5377 - 5385
[39] CHEMISTRY OF C-TRIMETHYLSILYL-SUBSTITUTED HETEROCARBORANES .9. REACTIVITY OF CLOSO-GERMA-PLUMBACARBORANES AND CLOSO-PLUMBACARBORANES TOWARD A MONODENTATE LEWIS BASE, (FERROCENYLMETHYL)DIMETHYLAMINE - SYNTHETIC, STRUCTURAL, AND BONDING STUDIES ON THE DONOR-ACCEPTOR COMPLEXES 1-M[(ETA-5-C5H5)FE(ETA-5-C5H4CH2(ME)2N)]-2-(SIME3)-3-R-2,3-C2B4H4 (M = GE, PB R = SIME3, ME, H)
HOSMANE, NS
LU, KJ
ZHANG, HM
MAGUIRE, JA
LEI, J
BARRETO, RD
ORGANOMETALLICS, 1992, 11 (07) : 2458 - 2467
[40] THE HETERONUCLEAR CLUSTER CHEMISTRY OF THE GROUP-1B METALS .7. SYNTHESIS AND AU-197 MOSSBAUER-SPECTRA OF THE MIXED-METAL CLUSTER COMPOUNDS [AU2RU4(MU-3-H)(MU-H)(MU-PH2E(CH2)NE'PH2)(CO)12] (N=1 OR 2, E = E' = AS OR E = AS, E' = P - N = 2, E = E' = P) - X-RAY CRYSTAL-STRUCTURE OF [AU2RU4(MU-3-H)(MU-H)(MU-PH2ASCH2PPH2)(CO)12])
BROWN, SSD
SALTER, ID
DYSON, DB
PARISH, RVD
BATES, PA
HURSTHOUSE, MB
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1988, (07): : 1795 - 1801

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