Carbonyl-metal fragment insertion into eight-vertex [closo-1-CB7H8]-.: Facile synthesis of ten-vertex metalladicarbollide complexes [2,2,2-(CO)3-1-OH-closo-2,1,10-MC2B7H8]n- {M = Fe, Ru (n=0), Mn, Re (n=1)}

被引：15

作者：

Franken, Andreas ^{[1
]}

Lei, Peng ^{[1
]}

McGrath, Thomas D. ^{[1
]}

Stone, F. Gordon A. ^{[1
]}

机构：

[1] Baylor Univ, Dept Chem & Biochem, Waco, TX 76798 USA

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 32期

关键词：

D O I：

10.1039/b607768d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Insertion of {M(CO)(4)} fragments (M = Fe, Ru, Mn, Re) into the eight-vertex monocarborane anion [closo-1-CB7H8](-) affords ten-vertex metal - dicarbollide complexes.

引用

页码：3423 / 3425

页数：3

共 47 条

[1] INCREMENTAL IODINATION OF THE EIGHT-VERTEX closo MONOCARBORANE ANION [closo-1-CB7H8]-: PREPARATION AND CHARACTERIZATION OF [closo-1-CB7H5-6,7,8-I3]- AND [closo-1-CB7H2-2,3,4,6,7,8-I6]-, AND THE SYNTHESIS OF THE FIRST EIGHT-VERTEX C-METHYLATED CARBORANE ANION [1-CH3-closo-1-CB7H4-6,7,8-I3]-
Dostal, Radim
Londesborough, Michael G. S.
Kvicalova, Magdalena
Machacek, Jan
Cisarova, Ivana
Janousek, Zbynek
COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 2010, 75 (09) : 931 - 947
[2] 10-Vertex Manganese-Dicarbollide Complexes from a Monocarbon Precursor. Synthesis and Cluster Vertex Functionalization of [1-OH-2,2,2-(CO)3-closo-2,1,10-MnC2B7H8]-
Franken, Andreas
McGrath, Thomas D.
Stone, F. Gordon A.
ORGANOMETALLICS, 2009, 28 (01) : 225 - 235
[3] A 10-vertex iron-dicarbollide system formed by insertion of {Fe(CO)4} into 8-vertex [closo-1-CB7H8]-:: Synthesis and reactivity studies
Franken, Andreas
McGrath, Thomas D.
Stone, F. Gordon A.
ORGANOMETALLICS, 2008, 27 (05) : 908 - 917
[4] Synthesis and characterization of novel monocarbollide exo-closo-(π-arene)biruthenacarboranes [(PPh3)mClRu(η6-C6H5R)Ru′CB10H11-n(OMe)n] (where R = H, m=2, n=1; R = μ-PPh2, m=1, n=0, 1)
Pisareva, IV
Konoplev, VE
Petrovskii, PV
Vorontsov, EV
Dolgushin, FM
Yanovsky, AI
Chizhevsky, IT
INORGANIC CHEMISTRY, 2004, 43 (20) : 6228 - 6237
[5] Synthesis and reactivity of the 13-vertex metallacarborane anions [4,4,4-(CO)3-closo-4,1,6-MC2B10H12]- (M = Re, Mn)
Hodson, BE
McGrath, TD
Stone, FGA
ORGANOMETALLICS, 2005, 24 (14) : 3386 - 3394
[6] CHEMISTRY OF C-TRIMETHYLSILYL-SUBSTITUTED MAIN-GROUP HETEROCARBORANES .7. REACTIVITY OF CLOSO-GERMACARBORANES AND CLOSO-PLUMBACARBORANES TOWARD A BIS(BIDENTATE) LEWIS BASE, 2,2'-BIPYRIMIDINE - SYNTHESES AND STRUCTURES OF 1 OR 1,1'-(2,2'-C8H6N4)[CLOSO-1-M-2-(ME3SI)-3-(R)-2,3-C2B4H4]N (N = 1, M = GE, N = 2, M = PB, R = ME3SI, ME, H)
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ORGANOMETALLICS, 1990, 9 (10) : 2798 - 2807
[7] A series of the twelve-vertex ferratricarbollides [2-(η5-C5H5)-9-X-closo-2,1,7,9-FeC3B8H10] (Where x = H2N, MeHN, Me2N, ButHN, But(Me)N).: A highly stable metallatricarbaborane system with amine functions in the para position to the metal center
Holub, J
Grüner, B
Císarová, I
Fusek, J
Plzák, Z
Teixidor, F
Viñas, C
Stíbr, B
INORGANIC CHEMISTRY, 1999, 38 (12) : 2775 - 2780
[8] Mononuclear carbonyl metal complexes of iron and ruthenium M(CO)n[P(C7H7)3] (M = Fe, Ru; n = 4,3,2), with the multidentate ligand tri-(1-cyclohepta-2,4,6-trienyl)phosphane
Herberhold, M
Bauer, K
Milius, W
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 563 (1-2) : 227 - 233
[9] Cobaltacarboranes [closo-( 9-R2N-1,7,9-C3B8H10)-commo-2,(3′)-Co-(1′,2′-C2B9H11)] (where R = H and Me) -: crossover complexes between metallatric arbollides and metalladicarbollides
Grüner, B
Teixidor, F
Viñas, C
Sillanpää, R
Kivekäs, R
Holub, J
Letonen, A
Stíbr, B
INORGANIC CHEMISTRY COMMUNICATIONS, 1999, 2 (09) : 411 - 413
[10] Electronic, Chemical, Thermodynamics Properties Screening of [M(SDPH)(VDPH)(X)a(Y)b)]n (M = Cr, Mn, Fe, Co, Ni; X = NH3; Y: H2O; a=0 or 1; b=1 or 2; n=0 or 1) Metal Complexes with an Extended Tight Binding Quantum Chemical Method
Pratiwi, Winda Eka
Mulyani, Irma
Ivansyah, Atthar Luqman
COMPUTATIONAL SCIENCE AND ITS APPLICATIONS, ICCSA 2022, PT II, 2022, 13376 : 314 - 332

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