Isochoric heat capacity cv of carbon dioxide and sulfur hexafluoride in the critical region

被引:15
|
作者
Beck, L [1 ]
Ernst, G [1 ]
Gürtner, J [1 ]
机构
[1] Univ Karlsruhe, Inst Tech Thermodynam, Fak Maschinenbau, Karlsruhe, Germany
来源
JOURNAL OF CHEMICAL THERMODYNAMICS | 2002年 / 34卷 / 03期
关键词
isochoric heat capacity; critical region; critical exponent alpha; CO2; SF6;
D O I
10.1006/jcht.2001.0955
中图分类号
O414.1 [热力学];
学科分类号
摘要
For a c(nu)-calorimeter of small dimensions, the procedure of measurement was changed from discontinuous to continuous to avoid heat loss and to increase the output of c(nu) data. Values of c(nu) were measured in the vicinity of the critical point. The critical exponent alpha was fitted to the values of c(nu) measured at nearly critical density. Results for c(nu) and alpha Of CO2 and SF6 are presented. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
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页码:277 / 292
页数:16
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